Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)

Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)

In the title complex, [MnCl2(C18H12N6)], the MnII ion is five-coordinated in an approximately square-pyramidal geometry defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two Cl atoms. In the crystal, the molecules are stacked in columns along the c axis and dis...

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Main Author: Kwang Ha
Format: Article
Language:English
Published: International Union of Crystallography 2010-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810004204
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spelling doaj-c545074c5d62465e951f37266868e24e2020-11-24T21:32:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-03-01663m262m26210.1107/S1600536810004204Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)Kwang HaIn the title complex, [MnCl2(C18H12N6)], the MnII ion is five-coordinated in an approximately square-pyramidal geometry defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two Cl atoms. In the crystal, the molecules are stacked in columns along the c axis and display intermolecular π–π interactions between the six-membered rings, the shortest centroid–centroid distance being 3.553 (3)Å. Intermolecular C—H...Cl contacts are also noted. http://scripts.iucr.org/cgi-bin/paper?S1600536810004204
collection DOAJ
language English
format Article
sources DOAJ
author Kwang Ha
spellingShingle Kwang Ha
Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
Acta Crystallographica Section E
author_facet Kwang Ha
author_sort Kwang Ha
title Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title_short Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title_full Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title_fullStr Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title_full_unstemmed Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title_sort dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-03-01
description In the title complex, [MnCl2(C18H12N6)], the MnII ion is five-coordinated in an approximately square-pyramidal geometry defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two Cl atoms. In the crystal, the molecules are stacked in columns along the c axis and display intermolecular π–π interactions between the six-membered rings, the shortest centroid–centroid distance being 3.553 (3)Å. Intermolecular C—H...Cl contacts are also noted.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810004204
work_keys_str_mv AT kwangha dichlorido246tri2pyridyl135triazinemanganeseii
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