{2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)

{2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)

In the title compound, [Cu(C20H12Br2N2O2)(CH3OH)], the CuII ion, and the C, O and hydroxy H atoms of the coordinated methanol molecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The CuII ion is coordinated by two N atoms [C...

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Main Author: Jianxin Xing
Format: Article
Language:English
Published: International Union of Crystallography 2009-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809011179
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spelling doaj-c4f4215602cc4823b8c2bb9449359d192020-11-25T01:35:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654m469m46910.1107/S1600536809011179{2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)Jianxin XingIn the title compound, [Cu(C20H12Br2N2O2)(CH3OH)], the CuII ion, and the C, O and hydroxy H atoms of the coordinated methanol molecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The CuII ion is coordinated by two N atoms [Cu—N = 1.960 (4) Å] and two O atoms [Cu—O = 1.908 (4) Å] from the tetradentate Schiff base ligand and by one O atom [Cu—O = 2.324 (6) Å] of the methanol molecule in a square-pyramidal geometry. In the crystal structure, intermolecular O—H...O hydrogen bonds link complex molecules into extended chains along [001]. http://scripts.iucr.org/cgi-bin/paper?S1600536809011179
collection DOAJ
language English
format Article
sources DOAJ
author Jianxin Xing
spellingShingle Jianxin Xing
{2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)
Acta Crystallographica Section E
author_facet Jianxin Xing
author_sort Jianxin Xing
title {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)
title_short {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)
title_full {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)
title_fullStr {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)
title_full_unstemmed {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)
title_sort {2,2′-[4,5-dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4o,n,n′,o′}(methanol-κo)copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-04-01
description In the title compound, [Cu(C20H12Br2N2O2)(CH3OH)], the CuII ion, and the C, O and hydroxy H atoms of the coordinated methanol molecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The CuII ion is coordinated by two N atoms [Cu—N = 1.960 (4) Å] and two O atoms [Cu—O = 1.908 (4) Å] from the tetradentate Schiff base ligand and by one O atom [Cu—O = 2.324 (6) Å] of the methanol molecule in a square-pyramidal geometry. In the crystal structure, intermolecular O—H...O hydrogen bonds link complex molecules into extended chains along [001].
url http://scripts.iucr.org/cgi-bin/paper?S1600536809011179
work_keys_str_mv AT jianxinxing 22amp824245dibromoophenylenebisnitrilodimethylidynediphenolatoamp9544onnamp8242oamp8242methanolamp954ocopperii
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