{2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)
In the title compound, [Cu(C20H12Br2N2O2)(CH3OH)], the CuII ion, and the C, O and hydroxy H atoms of the coordinated methanol molecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The CuII ion is coordinated by two N atoms [C...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809011179 |
| Summary: | In the title compound, [Cu(C20H12Br2N2O2)(CH3OH)], the CuII ion, and the C, O and hydroxy H atoms of the coordinated methanol molecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The CuII ion is coordinated by two N atoms [Cu—N = 1.960 (4) Å] and two O atoms [Cu—O = 1.908 (4) Å] from the tetradentate Schiff base ligand and by one O atom [Cu—O = 2.324 (6) Å] of the methanol molecule in a square-pyramidal geometry. In the crystal structure, intermolecular O—H...O hydrogen bonds link complex molecules into extended chains along [001]. |
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| ISSN: | 1600-5368 |