High-temperature hybrid phthalonitrile/amino-MMT nanocomposites: Synthesis, structure, properties

• Main Authors: V. A. Bershtein, A. M. Fainleib, P. N. Yakushev, D. A. Kirilenko, K. G. Gusakova, D. A. Markina, O. G. Melnychuk, V. A. Ryzhov
• Format: Article
• Language: English
• Published: Budapest University of Technology 2019-07-01
• Series: eXPRESS Polymer Letters
• Subjects: Nanocomposites; Phthalonitrile//amino-MMT; Synthesis; Structure; Properties
• Online Access: http://www.expresspolymlett.com/letolt.php?file=EPL-0009834&mi=cd

Hybrid nanocomposites based on heterocyclic network, obtained from bisphenol A based phthalonitrile (BAPhN) with different (0.03–5.0 wt%) contents of reactive amino-montmorillonite (MMT) nanolayers, were synthesized and studied for the first time. Their structure, dynamics, thermal, relaxation and elastic properties were characterized using transmission electron microscopy (TEM), mid-infrared (mid-IR), far-infrared (far-IR) and energy dispersive X-ray (EDX) spectroscopies, differential scanning calorimetry (DSC), and by dynamic mechanical analysis (DMA) and thermogravimetry (TGA) measurements performed in both air and nitrogen mediums at temperatures from 20 to 600–900 °C. Depending on nanofiller content, different extents of MMT stacks exfoliation, from single nanolayers to MMT stacks with tens nanolayers-thickness, are observed in the nanocomposites. The pronounced dynamic heterogeneity in the glass transition and the ‘constrained dynamics’ effects are shown. For the pristine matrix, Tg (DMA) = 446 °С varying from 460 to 570 °С for the nanocomposites. After high-temperature treatment in N2 medium, the relaxation spectrum and glass transition disappear, and constant dynamic modulus E′ ≈ 3 GPa at 20–600 °С is registered. A satisfactory thermal stability of the nanocomposites, with retaining the sample integrity is observed at temperatures up to ~500 °C in air and up to 900 °C in N2 medium.