Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex

Polarization change from directional electron transfer attracts considerable attention owing to its fast switching rate and potential light control. Here, the authors provide a proof-of-concept of electronic pyroelectricity induced by intramolecular electron transfer in the single crystal of a valen...

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Main Authors: Shu-Qi Wu, Meijiao Liu, Kaige Gao, Shinji Kanegawa, Yusuke Horie, Genki Aoyama, Hajime Okajima, Akira Sakamoto, Michael L. Baker, Myron S. Huzan, Peter Bencok, Tsukasa Abe, Yoshihito Shiota, Kazunari Yoshizawa, Wenhuang Xu, Hui-Zhong Kou, Osamu Sato
Format: Article
Language:English
Published: Nature Publishing Group 2020-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-15988-1
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spelling doaj-c4b8be37c47542ee8d81a90cea95c4962021-05-11T08:08:20ZengNature Publishing GroupNature Communications2041-17232020-04-011111810.1038/s41467-020-15988-1Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt ComplexShu-Qi Wu0Meijiao Liu1Kaige Gao2Shinji Kanegawa3Yusuke Horie4Genki Aoyama5Hajime Okajima6Akira Sakamoto7Michael L. Baker8Myron S. Huzan9Peter Bencok10Tsukasa Abe11Yoshihito Shiota12Kazunari Yoshizawa13Wenhuang Xu14Hui-Zhong Kou15Osamu Sato16Institute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityGraduate School of Science and Engineering, Aoyama Gakuin UniversityGraduate School of Science and Engineering, Aoyama Gakuin UniversityGraduate School of Science and Engineering, Aoyama Gakuin UniversityGraduate School of Science and Engineering, Aoyama Gakuin UniversityThe Department of Chemistry, The University of ManchesterThe Department of Chemistry, The University of ManchesterScience Division, Diamond Light SourceInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityDepartment of Chemistry, Tsinghua UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityPolarization change from directional electron transfer attracts considerable attention owing to its fast switching rate and potential light control. Here, the authors provide a proof-of-concept of electronic pyroelectricity induced by intramolecular electron transfer in the single crystal of a valence tautomeric compound.https://doi.org/10.1038/s41467-020-15988-1
collection DOAJ
language English
format Article
sources DOAJ
author Shu-Qi Wu
Meijiao Liu
Kaige Gao
Shinji Kanegawa
Yusuke Horie
Genki Aoyama
Hajime Okajima
Akira Sakamoto
Michael L. Baker
Myron S. Huzan
Peter Bencok
Tsukasa Abe
Yoshihito Shiota
Kazunari Yoshizawa
Wenhuang Xu
Hui-Zhong Kou
Osamu Sato
spellingShingle Shu-Qi Wu
Meijiao Liu
Kaige Gao
Shinji Kanegawa
Yusuke Horie
Genki Aoyama
Hajime Okajima
Akira Sakamoto
Michael L. Baker
Myron S. Huzan
Peter Bencok
Tsukasa Abe
Yoshihito Shiota
Kazunari Yoshizawa
Wenhuang Xu
Hui-Zhong Kou
Osamu Sato
Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex
Nature Communications
author_facet Shu-Qi Wu
Meijiao Liu
Kaige Gao
Shinji Kanegawa
Yusuke Horie
Genki Aoyama
Hajime Okajima
Akira Sakamoto
Michael L. Baker
Myron S. Huzan
Peter Bencok
Tsukasa Abe
Yoshihito Shiota
Kazunari Yoshizawa
Wenhuang Xu
Hui-Zhong Kou
Osamu Sato
author_sort Shu-Qi Wu
title Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex
title_short Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex
title_full Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex
title_fullStr Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex
title_full_unstemmed Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex
title_sort macroscopic polarization change via electron transfer in a valence tautomeric cobalt complex
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2020-04-01
description Polarization change from directional electron transfer attracts considerable attention owing to its fast switching rate and potential light control. Here, the authors provide a proof-of-concept of electronic pyroelectricity induced by intramolecular electron transfer in the single crystal of a valence tautomeric compound.
url https://doi.org/10.1038/s41467-020-15988-1
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