Thermal and Mechanical Analysis of Polyethylene Homo-Composites Processed by Rotational Molding

This work is aimed at studying the suitability of ultra-high molecular weight polyethylene (UHMWPE) fibers for the production of polyethylene homo-composites processed by rotational molding. Initially pre-impregnated bars were produced by co-extrusion and compression molding of UHMWPE fibers and lin...

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Bibliographic Details
Main Authors: Antonio Greco, Francesca Ferrari, Maria Grazia Buccoliero, Greta Trono
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/11/3/528
Description
Summary:This work is aimed at studying the suitability of ultra-high molecular weight polyethylene (UHMWPE) fibers for the production of polyethylene homo-composites processed by rotational molding. Initially pre-impregnated bars were produced by co-extrusion and compression molding of UHMWPE fibers and linear low-density polyethylene (LLDPE). A preliminary screening of different processing routes for the production of homo-composite reinforcing bars was performed, highlighting the relevance of fiber impregnation and crystalline structure on the mechanical properties. A combination of co-extrusion and compression molding was found to optimize the mechanical properties of the reinforcing bars, which were incorporated in the LLDPE matrix during a standard rotational molding process. Apart from fiber placement and an increase in processing time, processing of homo-composites did not require any modification of the existing production procedures. Plate bending tests performed on rotational molded homo-composites showed a modulus increase to a value three times higher than that of neat LLDPE. This increase was obtained by the addition of 4% of UHWMPE fibers and a negligible increase of the weight of the component. Dart impact tests also showed an increased toughness compared to neat LLPDE.
ISSN:2073-4360