The thermal decomposition of the pyridine saccharinates of Co, Ni and Cu: A correlation of the structural and the infrared data
In order to investigate the differences in the stability of the isomorphous pyridine saccharinates [Co(H2O)4(C5H5N)2](C7H4NO3S)2·H2O and [Ni(H2O)4(C5H5N)2[ (C7H4NO3S)2·4H2O, their thermal behavior (TG, DTG and DTA curves) from ambient temperature up to 1000°C in a static air atmosphere was studied....
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
1999-10-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol64/No10-Pdf/V64-no10-06.zip |
| Summary: | In order to investigate the differences in the stability of the isomorphous pyridine saccharinates [Co(H2O)4(C5H5N)2](C7H4NO3S)2·H2O and [Ni(H2O)4(C5H5N)2[ (C7H4NO3S)2·4H2O, their thermal behavior (TG, DTG and DTA curves) from ambient temperature up to 1000°C in a static air atmosphere was studied. For comparative purposes, the thermoanalytical curves of [Cu(H2O)(C5H5N)2(C7H4NO3S)2] were recorded as well. The decomposition pathways and the stability of the compounds are interpreted in the terms of the structural data. A possible mechanism for the decomposition of the saccharinato ion/ligand in an oxidizing atmosphere is proposed. The infrared spectral characteristics of the complexes are also discussed. |
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| ISSN: | 0352-5139 |