Solvent-vapour-assisted pathways and the role of pre-organization in solid-state transformations of coordination polymers

A family of one-dimensional coordination polymers, [Ag4(O2C(CF2)2CF3)4(phenazine)2(arene)n]·m(arene), 1 (arene = toluene or xylene), have been synthesized and crystallographically characterized. Arene guest loss invokes structural transformations to yield a pair of polymorphic coordination polymers...

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Bibliographic Details
Main Authors: James S. Wright, Iñigo J. Vitórica-Yrezábal, Harry Adams, Stephen P. Thompson, Adrian H. Hill, Lee Brammer
Format: Article
Language:English
Published: International Union of Crystallography 2015-03-01
Series:IUCrJ
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2052252515000147