[μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.18,12]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ8N3,N6,O23,O24:N14,N17,O23,O24]bis[(nitrato-κ2O,O′)nickel(II)]

In the title centrosymmetric dinuclear nickel complex, [Ni2(C22H30N4O2)(NO3)2], each of the two NiII atoms has a distorted octahedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion. The two Ni atoms are bridged by two pheno...

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Bibliographic Details
Main Authors: Ting-Ting Han, Jie Liu, Jian-Fang Ma, Quan-Jun Li
Format: Article
Language:English
Published: International Union of Crystallography 2009-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809010174
Description
Summary:In the title centrosymmetric dinuclear nickel complex, [Ni2(C22H30N4O2)(NO3)2], each of the two NiII atoms has a distorted octahedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion. The two Ni atoms are bridged by two phenolate O atoms, forming a four-membered Ni2O2 ring.
ISSN:1600-5368