A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine

A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine

A novel organic dianion, N,N'-Disulfo-1,4-benzoquinonediimine (1) has been prepared, which is a strong electron acceptor. The reduction potential of the PPh4 salt indicates that 1 is a stronger acceptor than DDQ (2,3-dichloro-5,6-dicyano-1,4-benzoquinone). The dianionic acceptor provided a BEDT...

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Bibliographic Details
Main Authors: Scott S. Turner, Shin’ichi Nakatsuji, Jun-ichi Yamada, Hiroki Akutsu
Format: Article
Language:English
Published: MDPI AG 2012-04-01
Series:Crystals
Subjects:
organic conductor
BEDT-TTF
hole doping effect
anionic acceptor
transport properties
magnetic properties
Online Access:http://www.mdpi.com/2073-4352/2/2/182/
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spelling doaj-c4259e061575408693e04a2482409b9e2020-11-24T20:54:51ZengMDPI AGCrystals2073-43522012-04-012218219210.3390/cryst2020182A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimineScott S. TurnerShin’ichi NakatsujiJun-ichi YamadaHiroki AkutsuA novel organic dianion, N,N'-Disulfo-1,4-benzoquinonediimine (1) has been prepared, which is a strong electron acceptor. The reduction potential of the PPh4 salt indicates that 1 is a stronger acceptor than DDQ (2,3-dichloro-5,6-dicyano-1,4-benzoquinone). The dianionic acceptor provided a BEDT-TTF salt, (BEDT-TTF)41·3H2O, the structures and physical properties of which are reported.http://www.mdpi.com/2073-4352/2/2/182/organic conductorBEDT-TTFhole doping effectanionic acceptortransport propertiesmagnetic properties
collection DOAJ
language English
format Article
sources DOAJ
author Scott S. Turner
Shin’ichi Nakatsuji
Jun-ichi Yamada
Hiroki Akutsu
spellingShingle Scott S. Turner
Shin’ichi Nakatsuji
Jun-ichi Yamada
Hiroki Akutsu
A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine
Crystals
organic conductor
BEDT-TTF
hole doping effect
anionic acceptor
transport properties
magnetic properties
author_facet Scott S. Turner
Shin’ichi Nakatsuji
Jun-ichi Yamada
Hiroki Akutsu
author_sort Scott S. Turner
title A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine
title_short A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine
title_full A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine
title_fullStr A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine
title_full_unstemmed A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine
title_sort new bedt-ttf-based organic charge transfer salt with a new anionic strong acceptor, n,n'-disulfo-1,4-benzoquinonediimine
publisher MDPI AG
series Crystals
issn 2073-4352
publishDate 2012-04-01
description A novel organic dianion, N,N'-Disulfo-1,4-benzoquinonediimine (1) has been prepared, which is a strong electron acceptor. The reduction potential of the PPh4 salt indicates that 1 is a stronger acceptor than DDQ (2,3-dichloro-5,6-dicyano-1,4-benzoquinone). The dianionic acceptor provided a BEDT-TTF salt, (BEDT-TTF)41·3H2O, the structures and physical properties of which are reported.
topic organic conductor
BEDT-TTF
hole doping effect
anionic acceptor
transport properties
magnetic properties
url http://www.mdpi.com/2073-4352/2/2/182/
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