Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2]
Interaction of [MoO2(acac)2] with internally functionalized oximes like HON=C(CH3)Ar (Ar = C4H3S, C4H3O or C5H4N) and Schiff's Bases derived from β – diketones like HOC(R)CHC(R′)=NC6H5 (R = R’ = CH3 or C6H5; R = CH3 and R’ = C6H5) led to the formation of yellow dioxomolybdenum(VI) complexes of...
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doaj-c3f994c9b659460693d28cd0ceda90222020-11-25T02:04:56ZengElsevierHeliyon2405-84402019-05-0155e01729Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2]Purnima Nag0Deepankar Sharma1Corresponding author.; Department of Chemistry, Jaipur National University, Jaipur, 302017, IndiaDepartment of Chemistry, Jaipur National University, Jaipur, 302017, IndiaInteraction of [MoO2(acac)2] with internally functionalized oximes like HON=C(CH3)Ar (Ar = C4H3S, C4H3O or C5H4N) and Schiff's Bases derived from β – diketones like HOC(R)CHC(R′)=NC6H5 (R = R’ = CH3 or C6H5; R = CH3 and R’ = C6H5) led to the formation of yellow dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R′)=NC6H5}2]. Oximes were synthesized by green methodology. The newly synthesized complexes were characterized on basis of elemental analysis and various spectral findings.Anticandidal activity of [MoO2{ON=C(CH3)C6H4N}2] clearly reveals that the complex is biologically active against fungal diseases.http://www.sciencedirect.com/science/article/pii/S2405844019300696Organic chemistryInorganic chemistryDioxomolybdenum(VI) complexesInternally functionalized oximesSchiff's bases derived from β – diketones |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Purnima Nag Deepankar Sharma |
| spellingShingle |
Purnima Nag Deepankar Sharma Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2] Heliyon Organic chemistry Inorganic chemistry Dioxomolybdenum(VI) complexes Internally functionalized oximes Schiff's bases derived from β – diketones |
| author_facet |
Purnima Nag Deepankar Sharma |
| author_sort |
Purnima Nag |
| title |
Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2] |
| title_short |
Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2] |
| title_full |
Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2] |
| title_fullStr |
Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2] |
| title_full_unstemmed |
Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2] |
| title_sort |
synthesis, characterization and anticandidal activity of dioxomolybdenum(vi) complexes of the type [moo2{on=c(ch3)ar}2] and [moo2{oc(r)chc(r’)=nc6h5}2] |
| publisher |
Elsevier |
| series |
Heliyon |
| issn |
2405-8440 |
| publishDate |
2019-05-01 |
| description |
Interaction of [MoO2(acac)2] with internally functionalized oximes like HON=C(CH3)Ar (Ar = C4H3S, C4H3O or C5H4N) and Schiff's Bases derived from β – diketones like HOC(R)CHC(R′)=NC6H5 (R = R’ = CH3 or C6H5; R = CH3 and R’ = C6H5) led to the formation of yellow dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R′)=NC6H5}2]. Oximes were synthesized by green methodology. The newly synthesized complexes were characterized on basis of elemental analysis and various spectral findings.Anticandidal activity of [MoO2{ON=C(CH3)C6H4N}2] clearly reveals that the complex is biologically active against fungal diseases. |
| topic |
Organic chemistry Inorganic chemistry Dioxomolybdenum(VI) complexes Internally functionalized oximes Schiff's bases derived from β – diketones |
| url |
http://www.sciencedirect.com/science/article/pii/S2405844019300696 |
| work_keys_str_mv |
AT purnimanag synthesischaracterizationandanticandidalactivityofdioxomolybdenumvicomplexesofthetypemoo2oncch3ar2andmoo2ocrchcrnc6h52 AT deepankarsharma synthesischaracterizationandanticandidalactivityofdioxomolybdenumvicomplexesofthetypemoo2oncch3ar2andmoo2ocrchcrnc6h52 |
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