(E)-1-(4-Aminophenyl)-3-[4-(benzyloxy)phenyl]prop-2-en-1-one

The title compound, C22H19NO2, crystallizes with two independent molecules (A and B) in the asymmetric unit. The benzyloxy ring in molecule A is disordered over two sets of sites, with a refined occupancy ratio of 0.665 (6):0.335 (6). Both molecules have an E conformation about the C=C bond of the p...

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Bibliographic Details
Main Authors: T. Hannah Clara, Johanan Christian Prasana, D. Reuben Jonathan, B. K. Revathi, G. Usha
Format: Article
Language:English
Published: International Union of Crystallography 2016-09-01
Series:IUCrData
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616013717
Description
Summary:The title compound, C22H19NO2, crystallizes with two independent molecules (A and B) in the asymmetric unit. The benzyloxy ring in molecule A is disordered over two sets of sites, with a refined occupancy ratio of 0.665 (6):0.335 (6). Both molecules have an E conformation about the C=C bond of the prop-2-en-1-one unit. In the major component of molecule A, the aminobenzene and benzyloxy rings are inclined to the central benzene ring by 20.12 (16) and 36.2 (3)°, respectively, and by 55.6 (3)° to one another. In molecule B, the corresponding dihedral angles are 23.65 (12), 10.24 (14) and 23.07 (14)°, respectively. In the crystal, the two molecules are linked by an N—H...O hydrogen bond. These A–B units are linked by N—H...π and C—H...π interactions, forming undulating sheets parallel to the ab plane.
ISSN:2414-3146