catena-Poly[[tribenzyltin(IV)]-μ-4-nitrocinnamato-κ2O:O′]

catena-Poly[[tribenzyltin(IV)]-μ-4-nitrocinnamato-κ2O:O′]

The 4-nitrocinnamate anion in the title compound, [Sn(C7H7)3(C9H6NO4)]n, bridges adjacent tribenzyltin cations into a helical chain running along the b axis. The Sn atoms in the two independent molecules adopt distorted trans-C3SnO2 trigonal–bipyramidal geometries. The repeat distance of t...

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Bibliographic Details
Main Authors: Pui Yee Thong, Kong Mun Lo, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2008-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808032236
Description
Summary:The 4-nitrocinnamate anion in the title compound, [Sn(C7H7)3(C9H6NO4)]n, bridges adjacent tribenzyltin cations into a helical chain running along the b axis. The Sn atoms in the two independent molecules adopt distorted trans-C3SnO2 trigonal–bipyramidal geometries. The repeat distance of the polymeric chain is b/2.
ISSN:1600-5368

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