Polymerization of Cyclic Esters Initiated by Carnitine and Tin (II) Octoate

Low-molecular weight poly(ε-caprolactone), polylactides and copolymers of ε-caprolactone and lactides were obtained by the polymerization of cyclic esters in the presence of a carnitine/SnOct2 system. Their structures were proven by means of MALDI-TOF, IR and NMR studies. Effects of temperature, rea...

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Bibliographic Details
Main Authors: Waclaw Kolodziejski, Marcin Sobczak
Format: Article
Language:English
Published: MDPI AG 2009-02-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/14/2/621/
Description
Summary:Low-molecular weight poly(ε-caprolactone), polylactides and copolymers of ε-caprolactone and lactides were obtained by the polymerization of cyclic esters in the presence of a carnitine/SnOct2 system. Their structures were proven by means of MALDI-TOF, IR and NMR studies. Effects of temperature, reaction time and carnitine dosage on the polymerization process were examined.
ISSN:1420-3049