Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)]
The crystal structure of the title complex, [Cu2(C15H10Cl2N2O2)2(C5H5N)2], features centrosymmetric dimers. The CuII ion is pentacoordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O′,N-tridentate ligand and a pyridine molecule. The fifth coordination site...
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International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811050720 |
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doaj-c1d71a96213f4b118eac1c1f2afa5c3f2020-11-25T00:54:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1886m188610.1107/S1600536811050720Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)]Jian-Guo ChangThe crystal structure of the title complex, [Cu2(C15H10Cl2N2O2)2(C5H5N)2], features centrosymmetric dimers. The CuII ion is pentacoordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O′,N-tridentate ligand and a pyridine molecule. The fifth coordination site is occupied by the O atom of another ligand showing a significantly longer Cu—O bond.http://scripts.iucr.org/cgi-bin/paper?S1600536811050720 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Jian-Guo Chang |
| spellingShingle |
Jian-Guo Chang Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)] Acta Crystallographica Section E |
| author_facet |
Jian-Guo Chang |
| author_sort |
Jian-Guo Chang |
| title |
Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)] |
| title_short |
Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)] |
| title_full |
Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)] |
| title_fullStr |
Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)] |
| title_full_unstemmed |
Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)] |
| title_sort |
bis{μ-4-chloro-n′-[(e)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(ii)] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-12-01 |
| description |
The crystal structure of the title complex, [Cu2(C15H10Cl2N2O2)2(C5H5N)2], features centrosymmetric dimers. The CuII ion is pentacoordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O′,N-tridentate ligand and a pyridine molecule. The fifth coordination site is occupied by the O atom of another ligand showing a significantly longer Cu—O bond. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811050720 |
| work_keys_str_mv |
AT jianguochang bisamp9564chloronamp8242e15chloro2oxidophenylethylidenebenzohydrazidatobispyridinecopperii |
| _version_ |
1725233637516902400 |