Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)]
The crystal structure of the title complex, [Cu2(C15H10Cl2N2O2)2(C5H5N)2], features centrosymmetric dimers. The CuII ion is pentacoordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O′,N-tridentate ligand and a pyridine molecule. The fifth coordination site...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811050720 |
| Summary: | The crystal structure of the title complex, [Cu2(C15H10Cl2N2O2)2(C5H5N)2], features centrosymmetric dimers. The CuII ion is pentacoordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O′,N-tridentate ligand and a pyridine molecule. The fifth coordination site is occupied by the O atom of another ligand showing a significantly longer Cu—O bond. |
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| ISSN: | 1600-5368 |