Effects of Iron Oxidation State and Chromium Distribution on the Corrosion Resistance of High Interstitial Stainless Steel for Down-Hole Application

The corrosion properties of Fe-Cr-Mn-C-N high interstitial austenitic stainless cast steels were investigated for down-hole application in sour environments. The two cast alloys contained 0.66% and 0.71% of total nitrogen and carbon. The corrosion properties of the alloys that were solution-treated...

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Main Authors: Hyunju Lee, Cheolmin Ahn, Walid Khalfaoui, Brajendra Mishra, Ilguk Jo, Eunkyung Lee
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/10/10/1302
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spelling doaj-c1d08c09f8ef4cdbb748fe076e68f95d2020-11-25T01:46:22ZengMDPI AGMetals2075-47012020-09-01101302130210.3390/met10101302Effects of Iron Oxidation State and Chromium Distribution on the Corrosion Resistance of High Interstitial Stainless Steel for Down-Hole ApplicationHyunju Lee0Cheolmin Ahn1Walid Khalfaoui2Brajendra Mishra3Ilguk Jo4Eunkyung Lee5Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources, Daejeon 34132, KoreaDepartment of Ocean Advanced Materials Convergence Engineering, Maritime and Ocean University, Busan 49112, KoreaDepartment of Chemical Engineering, Texas A&M University at Qatar, 23874 Doha, QatarDepartment of Mechanical Engineering, Worcester Polytechnic Institute, Worcester, MA 01609, USADepartment of Advanced Materials Engineering, Dong-Eui University, Busan 47340, KoreaDepartment of Ocean Advanced Materials Convergence Engineering, Maritime and Ocean University, Busan 49112, KoreaThe corrosion properties of Fe-Cr-Mn-C-N high interstitial austenitic stainless cast steels were investigated for down-hole application in sour environments. The two cast alloys contained 0.66% and 0.71% of total nitrogen and carbon. The corrosion properties of the alloys that were solution-treated and fast-cooled were directly responsible for high corrosion resistance in NaCl solution, including resistance to pitting corrosion resulting from a better distribution of chromium chemical compound in the high interstitial stainless cast steel. However, the sour corrosion resistance of the alloys decreased with the fast cooling rate, which can be attributed to the increased amount of ferrite containing Fe<sup>2+</sup>, which causes iron sulfide precipitate formation in H<sub>2</sub>S.https://www.mdpi.com/2075-4701/10/10/1302corrosion resistancechemical compoundbonding statushigh interstitial stainless cast steeldown-hole
collection DOAJ
language English
format Article
sources DOAJ
author Hyunju Lee
Cheolmin Ahn
Walid Khalfaoui
Brajendra Mishra
Ilguk Jo
Eunkyung Lee
spellingShingle Hyunju Lee
Cheolmin Ahn
Walid Khalfaoui
Brajendra Mishra
Ilguk Jo
Eunkyung Lee
Effects of Iron Oxidation State and Chromium Distribution on the Corrosion Resistance of High Interstitial Stainless Steel for Down-Hole Application
Metals
corrosion resistance
chemical compound
bonding status
high interstitial stainless cast steel
down-hole
author_facet Hyunju Lee
Cheolmin Ahn
Walid Khalfaoui
Brajendra Mishra
Ilguk Jo
Eunkyung Lee
author_sort Hyunju Lee
title Effects of Iron Oxidation State and Chromium Distribution on the Corrosion Resistance of High Interstitial Stainless Steel for Down-Hole Application
title_short Effects of Iron Oxidation State and Chromium Distribution on the Corrosion Resistance of High Interstitial Stainless Steel for Down-Hole Application
title_full Effects of Iron Oxidation State and Chromium Distribution on the Corrosion Resistance of High Interstitial Stainless Steel for Down-Hole Application
title_fullStr Effects of Iron Oxidation State and Chromium Distribution on the Corrosion Resistance of High Interstitial Stainless Steel for Down-Hole Application
title_full_unstemmed Effects of Iron Oxidation State and Chromium Distribution on the Corrosion Resistance of High Interstitial Stainless Steel for Down-Hole Application
title_sort effects of iron oxidation state and chromium distribution on the corrosion resistance of high interstitial stainless steel for down-hole application
publisher MDPI AG
series Metals
issn 2075-4701
publishDate 2020-09-01
description The corrosion properties of Fe-Cr-Mn-C-N high interstitial austenitic stainless cast steels were investigated for down-hole application in sour environments. The two cast alloys contained 0.66% and 0.71% of total nitrogen and carbon. The corrosion properties of the alloys that were solution-treated and fast-cooled were directly responsible for high corrosion resistance in NaCl solution, including resistance to pitting corrosion resulting from a better distribution of chromium chemical compound in the high interstitial stainless cast steel. However, the sour corrosion resistance of the alloys decreased with the fast cooling rate, which can be attributed to the increased amount of ferrite containing Fe<sup>2+</sup>, which causes iron sulfide precipitate formation in H<sub>2</sub>S.
topic corrosion resistance
chemical compound
bonding status
high interstitial stainless cast steel
down-hole
url https://www.mdpi.com/2075-4701/10/10/1302
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