Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvate

Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvate

In the title compound, [Ag(C7H6N2S)2]NO3·C3H6O, the AgI ion is coordinated to two benzothiazol-2-amine ligands via the thiazole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothiazole groups is 5.9 (3)&amp...

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Format: Article
Language:English
Published: International Union of Crystallography 2009-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809004176
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spelling doaj-c1cabb07d6fa44d3b881f3f5fbefa0972020-11-25T01:04:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653m265m26610.1107/S1600536809004176Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvateIn the title compound, [Ag(C7H6N2S)2]NO3·C3H6O, the AgI ion is coordinated to two benzothiazol-2-amine ligands via the thiazole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothiazole groups is 5.9 (3)°. Both amine groups on the ligands are oriented in the same direction and are engaged in N—H...O hydrogen bonding with the nitrate counter-anion, forming one-dimensional columns along the b-axis direction. Voids created by inefficient crystal packing are occupied by acetone solvent molecules which are disordered over two sites with occupancies of 0.563 (11) and 0.437 (11). http://scripts.iucr.org/cgi-bin/paper?S1600536809004176
collection DOAJ
language English
format Article
sources DOAJ
title Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvate
spellingShingle Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvate
Acta Crystallographica Section E
title_short Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvate
title_full Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvate
title_fullStr Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvate
title_full_unstemmed Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvate
title_sort bis(1,3-benzothiazol-2-amine-κn3)silver(i) nitrate acetone solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-03-01
description In the title compound, [Ag(C7H6N2S)2]NO3·C3H6O, the AgI ion is coordinated to two benzothiazol-2-amine ligands via the thiazole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothiazole groups is 5.9 (3)°. Both amine groups on the ligands are oriented in the same direction and are engaged in N—H...O hydrogen bonding with the nitrate counter-anion, forming one-dimensional columns along the b-axis direction. Voids created by inefficient crystal packing are occupied by acetone solvent molecules which are disordered over two sites with occupancies of 0.563 (11) and 0.437 (11).
url http://scripts.iucr.org/cgi-bin/paper?S1600536809004176
_version_ 1725197282347843584

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