Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvate
In the title compound, [Ag(C7H6N2S)2]NO3·C3H6O, the AgI ion is coordinated to two benzothiazol-2-amine ligands via the thiazole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothiazole groups is 5.9 (3)&...
| Format: | Article |
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| Language: | English |
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International Union of Crystallography
2009-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809004176 |
| Summary: | In the title compound, [Ag(C7H6N2S)2]NO3·C3H6O, the AgI ion is coordinated to two benzothiazol-2-amine ligands via the thiazole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothiazole groups is 5.9 (3)°. Both amine groups on the ligands are oriented in the same direction and are engaged in N—H...O hydrogen bonding with the nitrate counter-anion, forming one-dimensional columns along the b-axis direction. Voids created by inefficient crystal packing are occupied by acetone solvent molecules which are disordered over two sites with occupancies of 0.563 (11) and 0.437 (11). |
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| ISSN: | 1600-5368 |