Multivariate Modeling of Mechanical Properties for Hot Runner Molded Bioplastics and a Recycled Polypropylene Blend

• Main Authors: David O. Kazmer, Davide Masato, Leonardo Piccolo, Kyle Puleo, Joshua Krantz, Varun Venoor, Austin Colon, Justin Limkaichong, Neil Dewar, Denis Babin, Cheryl Sayer
• Format: Article
• Language: English
• Published: MDPI AG 2021-07-01
• Series: Sustainability
• Subjects: bioplastics; multivariate analysis; injection molding; thermal degradation
• Online Access: https://www.mdpi.com/2071-1050/13/14/8102

Four sustainable materials including a recycled polypropylene blend, polybutylene adipate terephthalate, and two grades of polylactic acid are compared to a reference isotactic polypropylene. Tensile specimens were produced using a two-cavity, hot runner mold with fully automatic cycles per standard industrial practices to investigate the effect of melt temperature, injection velocity, cycle time, and screw speed on the mechanical properties. Multiple regression and principal component analyses were performed for each of the materials. Results indicated that all the materials were readily processed using a hot runner, and the mechanical properties exhibited minimal variation. To the extent that losses in mechanical properties were observed, the results indicated that the losses were correlated with thermal degradation as independently characterized by thermal gravimetric analysis. Such losses can be minimized by reducing melt temperature and cycle time, leading to a reduction of the environmental impact of injection molding processes.