Base Catalyzed Cyclization and Isomerization of 3-Propargylmercapto-1, 2,4-Triazine to Thiazolo [3,2-b][1,2,4]-Triazines
Transformation of 3-propargylmercapto-6 methyl-1, 2,4-triazin- 5 (2H)- one (1; R=CH3) to 3,6- dimethyl-7H- thiazolo [3,2-b] [1, 2, 4] triazin -7- one (2) is performed under basic condition. The formation of (2) may be mainly due to the high reactivity of acetylenes towards nucleophiles and isomeriza...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
1992-12-01
|
| Series: | Iranian Journal of Chemistry & Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.ijcce.ac.ir/article_10954_d41d8cd98f00b204e9800998ecf8427e.pdf |
| id |
doaj-c120653141fa4ce9a27cd0e1c6d134c9 |
|---|---|
| record_format |
Article |
| spelling |
doaj-c120653141fa4ce9a27cd0e1c6d134c92020-11-25T03:41:49ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99861992-12-0111281110954Base Catalyzed Cyclization and Isomerization of 3-Propargylmercapto-1, 2,4-Triazine to Thiazolo [3,2-b][1,2,4]-TriazinesMajid Heravi0Department of Chemistry, Faculty of Sciences, Ferdowsi University, Mashhad, I.R. IRANTransformation of 3-propargylmercapto-6 methyl-1, 2,4-triazin- 5 (2H)- one (1; R=CH3) to 3,6- dimethyl-7H- thiazolo [3,2-b] [1, 2, 4] triazin -7- one (2) is performed under basic condition. The formation of (2) may be mainly due to the high reactivity of acetylenes towards nucleophiles and isomerization of the intermediate.http://www.ijcce.ac.ir/article_10954_d41d8cd98f00b204e9800998ecf8427e.pdfcyclizationisomerization3-propargylmercapto-124- triazinethiazolo [32-b][14]- triazine |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Majid Heravi |
| spellingShingle |
Majid Heravi Base Catalyzed Cyclization and Isomerization of 3-Propargylmercapto-1, 2,4-Triazine to Thiazolo [3,2-b][1,2,4]-Triazines Iranian Journal of Chemistry & Chemical Engineering cyclization isomerization 3-propargylmercapto-1 2 4- triazine thiazolo [3 2-b][1 4]- triazine |
| author_facet |
Majid Heravi |
| author_sort |
Majid Heravi |
| title |
Base Catalyzed Cyclization and Isomerization of 3-Propargylmercapto-1, 2,4-Triazine to Thiazolo [3,2-b][1,2,4]-Triazines |
| title_short |
Base Catalyzed Cyclization and Isomerization of 3-Propargylmercapto-1, 2,4-Triazine to Thiazolo [3,2-b][1,2,4]-Triazines |
| title_full |
Base Catalyzed Cyclization and Isomerization of 3-Propargylmercapto-1, 2,4-Triazine to Thiazolo [3,2-b][1,2,4]-Triazines |
| title_fullStr |
Base Catalyzed Cyclization and Isomerization of 3-Propargylmercapto-1, 2,4-Triazine to Thiazolo [3,2-b][1,2,4]-Triazines |
| title_full_unstemmed |
Base Catalyzed Cyclization and Isomerization of 3-Propargylmercapto-1, 2,4-Triazine to Thiazolo [3,2-b][1,2,4]-Triazines |
| title_sort |
base catalyzed cyclization and isomerization of 3-propargylmercapto-1, 2,4-triazine to thiazolo [3,2-b][1,2,4]-triazines |
| publisher |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
| series |
Iranian Journal of Chemistry & Chemical Engineering |
| issn |
1021-9986 1021-9986 |
| publishDate |
1992-12-01 |
| description |
Transformation of 3-propargylmercapto-6 methyl-1, 2,4-triazin- 5 (2H)- one (1; R=CH3) to 3,6- dimethyl-7H- thiazolo [3,2-b] [1, 2, 4] triazin -7- one (2) is performed under basic condition. The formation of (2) may be mainly due to the high reactivity of acetylenes towards nucleophiles and isomerization of the intermediate. |
| topic |
cyclization isomerization 3-propargylmercapto-1 2 4- triazine thiazolo [3 2-b][1 4]- triazine |
| url |
http://www.ijcce.ac.ir/article_10954_d41d8cd98f00b204e9800998ecf8427e.pdf |
| work_keys_str_mv |
AT majidheravi basecatalyzedcyclizationandisomerizationof3propargylmercapto124triazinetothiazolo32b124triazines |
| _version_ |
1724528120918179840 |