Meso-design of heterogeneous dielectric material systems: Structure property relationships

• Main Authors: Jeffrey Baker, Jon Michael Adkins, Fazle Rabbi, Qianlong Liu, Kenneth Reifsnider, Rassel Raihan
• Format: Article
• Language: English
• Published: World Scientific Publishing 2014-04-01
• Series: Journal of Advanced Dielectrics
• Subjects: Heterogeneous material systems; dielectric design; surface charge
• Online Access: http://www.worldscientific.com/doi/pdf/10.1142/S2010135X14500088
• ISSN: 2010-135X; 2010-1368

Heterogeneous materials are inherently dielectric, and charge distribution and transport in such materials involves complex local fields and polarizations that are remarkably sensitive to morphology and the interaction of conduction and permittivity. Trial and error design of such material systems is time consuming and expensive, and often ineffectual. However, heterogeneous materials are essential for energy conversion and storage, and they have become the foundation for major advances in the performance of devices such as batteries, fuel cells, separation membranes, and solar cells. The present paper presents some relationships in support of rational design based on an extensive experimental validation of the concepts and analysis that form a foundation for that design. Salient results include the prediction and confirmation of volume fraction effects (including nondilute mixtures), and the prediction and direct measurement of surface charge effects at internal interfaces as a function of constituent morphology and orientation.