μ-Oxido-bis[(2-chloronicotinato-κO)triphenylantimony(V)]

μ-Oxido-bis[(2-chloronicotinato-κO)triphenylantimony(V)]

A new dinuclear triphenylantimony(V) derivative with an oxide bridge, [Sb2(C6H5)6(C6H3ClNO2)2O], has been synthesized. Each Sb atom is five-coordianted by three C atoms and two O atoms in a distorted trigonal-bipyramidal geometry. Metal centers are bridged by a μ2-oxide functionality, and p...

Full description

Bibliographic Details
Main Authors: Li Quan, Handong Yin, Daqi Wang
Format: Article
Language:English
Published: International Union of Crystallography 2009-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808042335
id doaj-c0fd56281c134fbbb7c3b9d7db81b409
record_format Article
spelling doaj-c0fd56281c134fbbb7c3b9d7db81b4092020-11-25T01:27:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m99m9910.1107/S1600536808042335μ-Oxido-bis[(2-chloronicotinato-κO)triphenylantimony(V)]Li QuanHandong YinDaqi WangA new dinuclear triphenylantimony(V) derivative with an oxide bridge, [Sb2(C6H5)6(C6H3ClNO2)2O], has been synthesized. Each Sb atom is five-coordianted by three C atoms and two O atoms in a distorted trigonal-bipyramidal geometry. Metal centers are bridged by a μ2-oxide functionality, and phenyl substituents on Sb atoms are in an staggered arrangement. The Sb—O—Sb bridge displays a bent geometry with an angle of 165.1 (4)°. Molecules interact in the crystal through weak C—H...O and C—H...N intermolecular hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536808042335
collection DOAJ
language English
format Article
sources DOAJ
author Li Quan
Handong Yin
Daqi Wang
spellingShingle Li Quan
Handong Yin
Daqi Wang
μ-Oxido-bis[(2-chloronicotinato-κO)triphenylantimony(V)]
Acta Crystallographica Section E
author_facet Li Quan
Handong Yin
Daqi Wang
author_sort Li Quan
title μ-Oxido-bis[(2-chloronicotinato-κO)triphenylantimony(V)]
title_short μ-Oxido-bis[(2-chloronicotinato-κO)triphenylantimony(V)]
title_full μ-Oxido-bis[(2-chloronicotinato-κO)triphenylantimony(V)]
title_fullStr μ-Oxido-bis[(2-chloronicotinato-κO)triphenylantimony(V)]
title_full_unstemmed μ-Oxido-bis[(2-chloronicotinato-κO)triphenylantimony(V)]
title_sort μ-oxido-bis[(2-chloronicotinato-κo)triphenylantimony(v)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-01-01
description A new dinuclear triphenylantimony(V) derivative with an oxide bridge, [Sb2(C6H5)6(C6H3ClNO2)2O], has been synthesized. Each Sb atom is five-coordianted by three C atoms and two O atoms in a distorted trigonal-bipyramidal geometry. Metal centers are bridged by a μ2-oxide functionality, and phenyl substituents on Sb atoms are in an staggered arrangement. The Sb—O—Sb bridge displays a bent geometry with an angle of 165.1 (4)°. Molecules interact in the crystal through weak C—H...O and C—H...N intermolecular hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808042335
work_keys_str_mv AT liquan 956oxidobis2chloronicotinato954otriphenylantimonyv
AT handongyin 956oxidobis2chloronicotinato954otriphenylantimonyv
AT daqiwang 956oxidobis2chloronicotinato954otriphenylantimonyv
_version_ 1725103394795814912

Similar Items