Water-promoted C-S bond formation reactions
Despite the biological importance of sulfones, available synthetic methods usually involve toxic metals and reagents or harsh conditions. Here, the authors report an environmentally benign procedure for the metal-free carbon-sulfur bond formation of allylic sulfones in neutral aqueous medium at room...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Publishing Group
2018-04-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-018-03698-8 |
| id |
doaj-c0831286fa2a4e238e31d29f3298ec4a |
|---|---|
| record_format |
Article |
| spelling |
doaj-c0831286fa2a4e238e31d29f3298ec4a2021-05-11T09:21:14ZengNature Publishing GroupNature Communications2041-17232018-04-01911810.1038/s41467-018-03698-8Water-promoted C-S bond formation reactionsPeizhong Xie0Jinyu Wang1Yanan Liu2Jing Fan3Xiangyang Wo4Weishan Fu5Zuolian Sun6Teck-Peng Loh7School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversitySchool of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversitySchool of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversitySchool of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversitySchool of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversitySchool of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversitySchool of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversitySchool of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversityDespite the biological importance of sulfones, available synthetic methods usually involve toxic metals and reagents or harsh conditions. Here, the authors report an environmentally benign procedure for the metal-free carbon-sulfur bond formation of allylic sulfones in neutral aqueous medium at room temperature.https://doi.org/10.1038/s41467-018-03698-8 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Peizhong Xie Jinyu Wang Yanan Liu Jing Fan Xiangyang Wo Weishan Fu Zuolian Sun Teck-Peng Loh |
| spellingShingle |
Peizhong Xie Jinyu Wang Yanan Liu Jing Fan Xiangyang Wo Weishan Fu Zuolian Sun Teck-Peng Loh Water-promoted C-S bond formation reactions Nature Communications |
| author_facet |
Peizhong Xie Jinyu Wang Yanan Liu Jing Fan Xiangyang Wo Weishan Fu Zuolian Sun Teck-Peng Loh |
| author_sort |
Peizhong Xie |
| title |
Water-promoted C-S bond formation reactions |
| title_short |
Water-promoted C-S bond formation reactions |
| title_full |
Water-promoted C-S bond formation reactions |
| title_fullStr |
Water-promoted C-S bond formation reactions |
| title_full_unstemmed |
Water-promoted C-S bond formation reactions |
| title_sort |
water-promoted c-s bond formation reactions |
| publisher |
Nature Publishing Group |
| series |
Nature Communications |
| issn |
2041-1723 |
| publishDate |
2018-04-01 |
| description |
Despite the biological importance of sulfones, available synthetic methods usually involve toxic metals and reagents or harsh conditions. Here, the authors report an environmentally benign procedure for the metal-free carbon-sulfur bond formation of allylic sulfones in neutral aqueous medium at room temperature. |
| url |
https://doi.org/10.1038/s41467-018-03698-8 |
| work_keys_str_mv |
AT peizhongxie waterpromotedcsbondformationreactions AT jinyuwang waterpromotedcsbondformationreactions AT yananliu waterpromotedcsbondformationreactions AT jingfan waterpromotedcsbondformationreactions AT xiangyangwo waterpromotedcsbondformationreactions AT weishanfu waterpromotedcsbondformationreactions AT zuoliansun waterpromotedcsbondformationreactions AT teckpengloh waterpromotedcsbondformationreactions |
| _version_ |
1721450027176427520 |