Reações de oxidação de derivados de cis-octalinas promovidas por trinitrato de tálio (TTN) Oxidation reactions of derivatives of cis-octalins promoted by thallium trinitrate (TTN)

• Main Authors: Helena M. C. Ferraz, Vânia M. T. Carneiro, Tiago O. Vieira, Luiz F. Silva Jr.
• Format: Article
• Language: English
• Published: Sociedade Brasileira de Química 2008-01-01
• Series: Química Nova
• Subjects: thallium trinitrate; cis-hydrindanes; octalin
• Online Access: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000400014

<abstract language="eng">The reaction of ten cis-octalins and cis-octalones with thallium trinitrate (TTN) leads to different products, depending mainly on the substitution pattern of the substrate. Functionalized cis-hydrindanes were obtained from the reaction of 1,2,3,4,4a,5,8,8a-octahydro-4a-methylnaphthalene and of 1,2,3,4,4a,5,8,8a-octahydro-4a,7-dimethylnaphthalene with TTN in acetonitrile, whereas a cyclic ether was formed treating 1,2,3,4,4a,5,8,8a-octahydro-6,8a-dimethylnaphthalen-1-ol with TTN in trimethylorthoformate (TMOF).