Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ2N3:N3′]diformatomanganese(II)]

Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ2N3:N3′]diformatomanganese(II)]

In the title compound, [Mn(CHO2)2(C12H10N4)2]n, the MnII atom and the benzene ring of the ligand lie on an inversion centers. The MnII atom has an octahedral coordination environment composed of four N atoms from two different symmetry-related N-heterocyclic ligands forming the basal plane, and two...

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Main Authors: Shui-Sheng Chen, Sen-Lin Yang, Shu-Ping Zhang, Zi-Qiang Lu
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810044053
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spelling doaj-c05d62c335f84251a291d57305587b2e2020-11-25T02:19:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1501m150210.1107/S1600536810044053Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ2N3:N3′]diformatomanganese(II)]Shui-Sheng ChenSen-Lin YangShu-Ping ZhangZi-Qiang LuIn the title compound, [Mn(CHO2)2(C12H10N4)2]n, the MnII atom and the benzene ring of the ligand lie on an inversion centers. The MnII atom has an octahedral coordination environment composed of four N atoms from two different symmetry-related N-heterocyclic ligands forming the basal plane, and two O atoms from symmetry-related formate anions occupying the apical positions. The title compound forms a two-dimensional (4,4) net parallel to (100) with all the MnII atoms lying on a plane. The crystal structure is consolidated by intermolecular N—H...O hydrogen bonds.. http://scripts.iucr.org/cgi-bin/paper?S1600536810044053
collection DOAJ
language English
format Article
sources DOAJ
author Shui-Sheng Chen
Sen-Lin Yang
Shu-Ping Zhang
Zi-Qiang Lu
spellingShingle Shui-Sheng Chen
Sen-Lin Yang
Shu-Ping Zhang
Zi-Qiang Lu
Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ2N3:N3′]diformatomanganese(II)]
Acta Crystallographica Section E
author_facet Shui-Sheng Chen
Sen-Lin Yang
Shu-Ping Zhang
Zi-Qiang Lu
author_sort Shui-Sheng Chen
title Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ2N3:N3′]diformatomanganese(II)]
title_short Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ2N3:N3′]diformatomanganese(II)]
title_full Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ2N3:N3′]diformatomanganese(II)]
title_fullStr Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ2N3:N3′]diformatomanganese(II)]
title_full_unstemmed Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ2N3:N3′]diformatomanganese(II)]
title_sort poly[bis[μ-1,4-bis(1h-imidazol-5-yl)benzene-κ2n3:n3′]diformatomanganese(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description In the title compound, [Mn(CHO2)2(C12H10N4)2]n, the MnII atom and the benzene ring of the ligand lie on an inversion centers. The MnII atom has an octahedral coordination environment composed of four N atoms from two different symmetry-related N-heterocyclic ligands forming the basal plane, and two O atoms from symmetry-related formate anions occupying the apical positions. The title compound forms a two-dimensional (4,4) net parallel to (100) with all the MnII atoms lying on a plane. The crystal structure is consolidated by intermolecular N—H...O hydrogen bonds..
url http://scripts.iucr.org/cgi-bin/paper?S1600536810044053
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AT senlinyang polybisamp95614bis1himidazol5ylbenzeneamp9542n3n3amp8242diformatomanganeseii
AT shupingzhang polybisamp95614bis1himidazol5ylbenzeneamp9542n3n3amp8242diformatomanganeseii
AT ziqianglu polybisamp95614bis1himidazol5ylbenzeneamp9542n3n3amp8242diformatomanganeseii
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