Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests

Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests

The inclusion of volatile derivatives of benzene and cyclohexane in β-cyclodextrin (β-CD), hydroxypropyl-β-CD, and hydrophilic β-CD-thioethers was investigated by static headspace gas chromatography (HS-GC) and molecular modelling. The obtained binding constants strongly increase with the amount of...

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Bibliographic Details
Main Authors: Sophie Fourmentin, Anca Ciobanu, David Landy, Gerhard Wenz
Format: Article
Language:English
Published: Beilstein-Institut 2013-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
cyclodextrins
inclusion compound
molecular modelling
space filling
static headspace gas chromatography
vapor pressure
Online Access:https://doi.org/10.3762/bjoc.9.133
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spelling doaj-c049e3940a30440f8cb991dc3b74175c2021-02-02T01:57:46ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972013-06-01911185119110.3762/bjoc.9.1331860-5397-9-133Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guestsSophie Fourmentin0Anca Ciobanu1David Landy2Gerhard Wenz3University Lille Nord de France, F-59000 Lille, FranceUniversity Lille Nord de France, F-59000 Lille, FranceUniversity Lille Nord de France, F-59000 Lille, FranceOrganic Macromolecular Chemistry, Saarland University, Campus Saarbrücken C4 2, 66123 Saarbrücken, GermanyThe inclusion of volatile derivatives of benzene and cyclohexane in β-cyclodextrin (β-CD), hydroxypropyl-β-CD, and hydrophilic β-CD-thioethers was investigated by static headspace gas chromatography (HS-GC) and molecular modelling. The obtained binding constants strongly increase with the amount of space filling of the CD cavity and the salt concentration. β-CD thioethers show a 3–10 times higher binding potential than native β-CD.https://doi.org/10.3762/bjoc.9.133cyclodextrinsinclusion compoundmolecular modellingspace fillingstatic headspace gas chromatographyvapor pressure
collection DOAJ
language English
format Article
sources DOAJ
author Sophie Fourmentin
Anca Ciobanu
David Landy
Gerhard Wenz
spellingShingle Sophie Fourmentin
Anca Ciobanu
David Landy
Gerhard Wenz
Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests
Beilstein Journal of Organic Chemistry
cyclodextrins
inclusion compound
molecular modelling
space filling
static headspace gas chromatography
vapor pressure
author_facet Sophie Fourmentin
Anca Ciobanu
David Landy
Gerhard Wenz
author_sort Sophie Fourmentin
title Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests
title_short Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests
title_full Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests
title_fullStr Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests
title_full_unstemmed Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests
title_sort space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2013-06-01
description The inclusion of volatile derivatives of benzene and cyclohexane in β-cyclodextrin (β-CD), hydroxypropyl-β-CD, and hydrophilic β-CD-thioethers was investigated by static headspace gas chromatography (HS-GC) and molecular modelling. The obtained binding constants strongly increase with the amount of space filling of the CD cavity and the salt concentration. β-CD thioethers show a 3–10 times higher binding potential than native β-CD.
topic cyclodextrins
inclusion compound
molecular modelling
space filling
static headspace gas chromatography
vapor pressure
url https://doi.org/10.3762/bjoc.9.133
work_keys_str_mv AT sophiefourmentin spacefillingofbcyclodextrinandbcyclodextrinderivativesbyvolatilehydrophobicguests
AT ancaciobanu spacefillingofbcyclodextrinandbcyclodextrinderivativesbyvolatilehydrophobicguests
AT davidlandy spacefillingofbcyclodextrinandbcyclodextrinderivativesbyvolatilehydrophobicguests
AT gerhardwenz spacefillingofbcyclodextrinandbcyclodextrinderivativesbyvolatilehydrophobicguests
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