2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES
We generalized the experimental data and proposed optimal synthesis techniques and methods for growing crystals 25 homo- and heteronuclear complex of germanium (IV) and a series of s-, d-, f-metals with 2-hydroxypropylene-1,3-diamine-N,N,Nʹ,Nʹ-tetraacetic acid (H5Hpdta). Determined their spectral pr...
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Odessa I. I. Mechnikov National University
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Online Access: | http://heraldchem.onu.edu.ua/article/view/6-19 |
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doaj-bfea8ee4197d429d96510f71a1cce13b2020-11-24T23:50:11ZengOdessa I. I. Mechnikov National University Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ2304-09472414-59632015-04-01193(51)61910.18524/2304-0947.2014.3(51).403216-192-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURESE. E. Martsinko0Одеський національний університет імені І.І. Мечникова, кафедра загальної хімії та полімерівWe generalized the experimental data and proposed optimal synthesis techniques and methods for growing crystals 25 homo- and heteronuclear complex of germanium (IV) and a series of s-, d-, f-metals with 2-hydroxypropylene-1,3-diamine-N,N,Nʹ,Nʹ-tetraacetic acid (H5Hpdta). Determined their spectral properties and thermal stability are described features of the structure. We compared characteristics of the synthesized 2-hydroxypropylene-1,3-diamine- N,N,Nʹ,Nʹ-tetraacetagermanatics depending on the electronic structure of the second metal. Have been discovered laws of formation on the basis of the complex anion [Ge(Н2О)(ОН) (Hpdta)]2– different types of supramolecular compounds: cation-anion, heterobinuclear and tetranuclear.http://heraldchem.onu.edu.ua/article/view/6-19діоксид германію, комплексони, гетероядерні комплексонати, координаційні сполуки |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
E. E. Martsinko |
spellingShingle |
E. E. Martsinko 2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ діоксид германію, комплексони, гетероядерні комплексонати, координаційні сполуки |
author_facet |
E. E. Martsinko |
author_sort |
E. E. Martsinko |
title |
2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES |
title_short |
2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES |
title_full |
2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES |
title_fullStr |
2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES |
title_full_unstemmed |
2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES |
title_sort |
2-hydroxypropyl-1,3-diamintetraacet agermanatics:synthesis, properties, structural features |
publisher |
Odessa I. I. Mechnikov National University |
series |
Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ |
issn |
2304-0947 2414-5963 |
publishDate |
2015-04-01 |
description |
We generalized the experimental data and proposed optimal synthesis techniques and methods for growing crystals 25 homo- and heteronuclear complex of germanium (IV) and a series of s-, d-, f-metals with 2-hydroxypropylene-1,3-diamine-N,N,Nʹ,Nʹ-tetraacetic acid (H5Hpdta). Determined their spectral properties and thermal stability are described features of the structure. We compared characteristics of the synthesized 2-hydroxypropylene-1,3-diamine- N,N,Nʹ,Nʹ-tetraacetagermanatics depending on the electronic structure of the second metal. Have been discovered laws of formation on the basis of the complex anion [Ge(Н2О)(ОН) (Hpdta)]2– different types of supramolecular compounds: cation-anion, heterobinuclear and tetranuclear. |
topic |
діоксид германію, комплексони, гетероядерні комплексонати, координаційні сполуки |
url |
http://heraldchem.onu.edu.ua/article/view/6-19 |
work_keys_str_mv |
AT eemartsinko 2hydroxypropyl13diamintetraacetagermanaticssynthesispropertiesstructuralfeatures |
_version_ |
1725479720386035712 |