2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES

We generalized the experimental data and proposed optimal synthesis techniques and methods for growing crystals 25 homo- and heteronuclear complex of germanium (IV) and a series of s-, d-, f-metals with 2-hydroxypropylene-1,3-diamine-N,N,Nʹ,Nʹ-tetraacetic acid (H5Hpdta). Determined their spectral pr...

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Main Author: E. E. Martsinko
Format: Article
Language:English
Published: Odessa I. I. Mechnikov National University 2015-04-01
Series:Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
Subjects:
Online Access:http://heraldchem.onu.edu.ua/article/view/6-19
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spelling doaj-bfea8ee4197d429d96510f71a1cce13b2020-11-24T23:50:11ZengOdessa I. I. Mechnikov National University Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ2304-09472414-59632015-04-01193(51)61910.18524/2304-0947.2014.3(51).403216-192-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURESE. E. Martsinko0Одеський національний університет імені І.І. Мечникова, кафедра загальної хімії та полімерівWe generalized the experimental data and proposed optimal synthesis techniques and methods for growing crystals 25 homo- and heteronuclear complex of germanium (IV) and a series of s-, d-, f-metals with 2-hydroxypropylene-1,3-diamine-N,N,Nʹ,Nʹ-tetraacetic acid (H5Hpdta). Determined their spectral properties and thermal stability are described features of the structure. We compared characteristics of the synthesized 2-hydroxypropylene-1,3-diamine- N,N,Nʹ,Nʹ-tetraacetagermanatics depending on the electronic structure of the second metal. Have been discovered laws of formation on the basis of the complex anion [Ge(Н2О)(ОН) (Hpdta)]2– different types of supramolecular compounds: cation-anion, heterobinuclear and tetranuclear.http://heraldchem.onu.edu.ua/article/view/6-19діоксид германію, комплексони, гетероядерні комплексонати, координаційні сполуки
collection DOAJ
language English
format Article
sources DOAJ
author E. E. Martsinko
spellingShingle E. E. Martsinko
2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES
Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
діоксид германію, комплексони, гетероядерні комплексонати, координаційні сполуки
author_facet E. E. Martsinko
author_sort E. E. Martsinko
title 2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES
title_short 2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES
title_full 2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES
title_fullStr 2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES
title_full_unstemmed 2-HYDROXYPROPYL-1,3-DIAMINTETRAACET AGERMANATICS:SYNTHESIS, PROPERTIES, STRUCTURAL FEATURES
title_sort 2-hydroxypropyl-1,3-diamintetraacet agermanatics:synthesis, properties, structural features
publisher Odessa I. I. Mechnikov National University
series Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
issn 2304-0947
2414-5963
publishDate 2015-04-01
description We generalized the experimental data and proposed optimal synthesis techniques and methods for growing crystals 25 homo- and heteronuclear complex of germanium (IV) and a series of s-, d-, f-metals with 2-hydroxypropylene-1,3-diamine-N,N,Nʹ,Nʹ-tetraacetic acid (H5Hpdta). Determined their spectral properties and thermal stability are described features of the structure. We compared characteristics of the synthesized 2-hydroxypropylene-1,3-diamine- N,N,Nʹ,Nʹ-tetraacetagermanatics depending on the electronic structure of the second metal. Have been discovered laws of formation on the basis of the complex anion [Ge(Н2О)(ОН) (Hpdta)]2– different types of supramolecular compounds: cation-anion, heterobinuclear and tetranuclear.
topic діоксид германію, комплексони, гетероядерні комплексонати, координаційні сполуки
url http://heraldchem.onu.edu.ua/article/view/6-19
work_keys_str_mv AT eemartsinko 2hydroxypropyl13diamintetraacetagermanaticssynthesispropertiesstructuralfeatures
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