2,4-Diamino-6-methyl-1,3,5-triazin-1-ium hydrogen oxalate

2,4-Diamino-6-methyl-1,3,5-triazin-1-ium hydrogen oxalate

The title compound, C4H8N5+·C2HO4−, was obtained from the reaction of oxalic acid and 2,4-diamino-6-methyl-1,3,5-triazine. The protonated triazine ring is essentially planar with a maximum deviation of 0.035 (1) Å, but the hydrogen...

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Main Authors: Bohari M. Yamin, Leila Narimani
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812016637
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spelling doaj-bf85479b25e54441b1945b692f27a58b2020-11-25T00:27:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685o1475o147510.1107/S16005368120166372,4-Diamino-6-methyl-1,3,5-triazin-1-ium hydrogen oxalateBohari M. YaminLeila NarimaniThe title compound, C4H8N5+·C2HO4−, was obtained from the reaction of oxalic acid and 2,4-diamino-6-methyl-1,3,5-triazine. The protonated triazine ring is essentially planar with a maximum deviation of 0.035 (1) Å, but the hydrogen oxalate anion is less planar, with a maximum deviation of 0.131 (1) Å for both carbonyl O atoms. In the crystal, the ions are linked by intermolecular N—H...O, N—H...N, O—H...O and C—H...O hydrogen bonds, forming a three-dimensional network. Weak π–π [centroid–centroid distance = 3.763 Å] and C—O...π interactions [O...centroid = 3.5300 (16) Å, C—O...centroid = 132.19 (10)°] are also present.http://scripts.iucr.org/cgi-bin/paper?S1600536812016637
collection DOAJ
language English
format Article
sources DOAJ
author Bohari M. Yamin
Leila Narimani
spellingShingle Bohari M. Yamin
Leila Narimani
2,4-Diamino-6-methyl-1,3,5-triazin-1-ium hydrogen oxalate
Acta Crystallographica Section E
author_facet Bohari M. Yamin
Leila Narimani
author_sort Bohari M. Yamin
title 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium hydrogen oxalate
title_short 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium hydrogen oxalate
title_full 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium hydrogen oxalate
title_fullStr 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium hydrogen oxalate
title_full_unstemmed 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium hydrogen oxalate
title_sort 2,4-diamino-6-methyl-1,3,5-triazin-1-ium hydrogen oxalate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-05-01
description The title compound, C4H8N5+·C2HO4−, was obtained from the reaction of oxalic acid and 2,4-diamino-6-methyl-1,3,5-triazine. The protonated triazine ring is essentially planar with a maximum deviation of 0.035 (1) Å, but the hydrogen oxalate anion is less planar, with a maximum deviation of 0.131 (1) Å for both carbonyl O atoms. In the crystal, the ions are linked by intermolecular N—H...O, N—H...N, O—H...O and C—H...O hydrogen bonds, forming a three-dimensional network. Weak π–π [centroid–centroid distance = 3.763 Å] and C—O...π interactions [O...centroid = 3.5300 (16) Å, C—O...centroid = 132.19 (10)°] are also present.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812016637
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AT leilanarimani 24diamino6methyl135triazin1iumhydrogenoxalate
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