{2-[Bis(3-methyl-1H-indol-2-yl)methyl]phenolato-κO}dimethyl(tetrahydrofuran-κO)aluminium(III)
The title compound, [Al(CH3)2(C25H21N2O)(C4H8O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethylaluminum in tetrahydrofuran. The ligands adopt a distorted tetrahedral geometry around aluminium. Obvious hydrogen-bonding interactions are not presen...
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International Union of Crystallography
2009-11-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809040598 |
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doaj-bf4a365061884521b39088dadbf191862020-11-25T02:16:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1353m135310.1107/S1600536809040598{2-[Bis(3-methyl-1H-indol-2-yl)methyl]phenolato-κO}dimethyl(tetrahydrofuran-κO)aluminium(III)Audrey C. EisenbergJoseph M. TanskiYutan D. Y. L. GetzlerThe title compound, [Al(CH3)2(C25H21N2O)(C4H8O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethylaluminum in tetrahydrofuran. The ligands adopt a distorted tetrahedral geometry around aluminium. Obvious hydrogen-bonding interactions are not present. http://scripts.iucr.org/cgi-bin/paper?S1600536809040598 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Audrey C. Eisenberg Joseph M. Tanski Yutan D. Y. L. Getzler |
spellingShingle |
Audrey C. Eisenberg Joseph M. Tanski Yutan D. Y. L. Getzler {2-[Bis(3-methyl-1H-indol-2-yl)methyl]phenolato-κO}dimethyl(tetrahydrofuran-κO)aluminium(III) Acta Crystallographica Section E |
author_facet |
Audrey C. Eisenberg Joseph M. Tanski Yutan D. Y. L. Getzler |
author_sort |
Audrey C. Eisenberg |
title |
{2-[Bis(3-methyl-1H-indol-2-yl)methyl]phenolato-κO}dimethyl(tetrahydrofuran-κO)aluminium(III) |
title_short |
{2-[Bis(3-methyl-1H-indol-2-yl)methyl]phenolato-κO}dimethyl(tetrahydrofuran-κO)aluminium(III) |
title_full |
{2-[Bis(3-methyl-1H-indol-2-yl)methyl]phenolato-κO}dimethyl(tetrahydrofuran-κO)aluminium(III) |
title_fullStr |
{2-[Bis(3-methyl-1H-indol-2-yl)methyl]phenolato-κO}dimethyl(tetrahydrofuran-κO)aluminium(III) |
title_full_unstemmed |
{2-[Bis(3-methyl-1H-indol-2-yl)methyl]phenolato-κO}dimethyl(tetrahydrofuran-κO)aluminium(III) |
title_sort |
{2-[bis(3-methyl-1h-indol-2-yl)methyl]phenolato-κo}dimethyl(tetrahydrofuran-κo)aluminium(iii) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2009-11-01 |
description |
The title compound, [Al(CH3)2(C25H21N2O)(C4H8O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethylaluminum in tetrahydrofuran. The ligands adopt a distorted tetrahedral geometry around aluminium. Obvious hydrogen-bonding interactions are not present. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809040598 |
work_keys_str_mv |
AT audreyceisenberg 2bis3methyl1hindol2ylmethylphenolatoamp954odimethyltetrahydrofuranamp954oaluminiumiii AT josephmtanski 2bis3methyl1hindol2ylmethylphenolatoamp954odimethyltetrahydrofuranamp954oaluminiumiii AT yutandylgetzler 2bis3methyl1hindol2ylmethylphenolatoamp954odimethyltetrahydrofuranamp954oaluminiumiii |
_version_ |
1724889132356861952 |