Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate

Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate

In the title compound, [Au(C9H9N)2]BF4, the AuI cation adopts an almost linear AuC2 geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°.

Bibliographic Details
Main Authors: Clifford P. Kubiak, Arnold L. Rheingold, Antonio G. DiPasquale, Timi P. Singa
Format: Article
Language:English
Published: International Union of Crystallography 2008-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808027116
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spelling doaj-bf34e324e218485b815b3f4b9dabf3e72020-11-25T02:01:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1221m122110.1107/S1600536808027116Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborateClifford P. KubiakArnold L. RheingoldAntonio G. DiPasqualeTimi P. SingaIn the title compound, [Au(C9H9N)2]BF4, the AuI cation adopts an almost linear AuC2 geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°.http://scripts.iucr.org/cgi-bin/paper?S1600536808027116
collection DOAJ
language English
format Article
sources DOAJ
author Clifford P. Kubiak
Arnold L. Rheingold
Antonio G. DiPasquale
Timi P. Singa
spellingShingle Clifford P. Kubiak
Arnold L. Rheingold
Antonio G. DiPasquale
Timi P. Singa
Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate
Acta Crystallographica Section E
author_facet Clifford P. Kubiak
Arnold L. Rheingold
Antonio G. DiPasquale
Timi P. Singa
author_sort Clifford P. Kubiak
title Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate
title_short Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate
title_full Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate
title_fullStr Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate
title_full_unstemmed Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate
title_sort bis(2,6-dimethylphenyl isocyanide-κc)gold(i) tetrafluoridoborate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-10-01
description In the title compound, [Au(C9H9N)2]BF4, the AuI cation adopts an almost linear AuC2 geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808027116
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AT arnoldlrheingold bis26dimethylphenylisocyanide954cgolditetrafluoridoborate
AT antoniogdipasquale bis26dimethylphenylisocyanide954cgolditetrafluoridoborate
AT timipsinga bis26dimethylphenylisocyanide954cgolditetrafluoridoborate
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