Stereochemistry of ring-opening/cross metathesis reactions of exo- and endo-7-oxabicyclo[2.2.1]hept-5-ene-2-carbonitriles with allyl alcohol and allyl acetate

Stereochemistry of ring-opening/cross metathesis reactions of exo- and endo-7-oxabicyclo[2.2.1]hept-5-ene-2-carbonitriles with allyl alcohol and allyl acetate

The ROCM reactions of exo- and endo-2-cyano-7-oxanorbornenes with allyl alcohol or allyl acetate promoted by different ruthenium alkylidene catalysts were studied. The stereochemical outcome of the reactions was established. The issues concerning chemo- (ROCM vs ROMP), regio- (1-2- vs 1-3-product fo...

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Bibliographic Details
Main Authors: Piotr Wałejko, Michał Dąbrowski, Lech Szczepaniak, Jacek W. Morzycki, Stanisław Witkowski
Format: Article
Language:English
Published: Beilstein-Institut 2015-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Grubbs’ catalysts
metathesis
ROCM
ROMP
Z-selectivity
Online Access:https://doi.org/10.3762/bjoc.11.204

Internet

https://doi.org/10.3762/bjoc.11.204

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