Crystal structure and Hirshfeld surface analysis of (3Z)-7-methoxy-3-(2-phenylhydrazinylidene)-1-benzofuran-2(3H)-one

Crystal structure and Hirshfeld surface analysis of (3Z)-7-methoxy-3-(2-phenylhydrazinylidene)-1-benzofuran-2(3H)-one

In the title compound, C15H12N2O3, pairs of molecules are linked into dimers by N—H...O hydrogen bonds, forming an R22(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π–π stacking interactions between the centroids of the benzene and furan rings of their...

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Bibliographic Details
Main Authors: Zeliha Atioğlu, Mehmet Akkurt, Ulviyya F. Askerova, Sevinc H. Mukhtarova, Rizvan K. Askerov, Sixberth Mlowe
Format: Article
Language:English
Published: International Union of Crystallography 2021-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
2,3-dihydro-1-benzofuran ring system
dimers
hydrogen bonds
hirshfeld surface analysis
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989021007891
Description
Summary:In the title compound, C15H12N2O3, pairs of molecules are linked into dimers by N—H...O hydrogen bonds, forming an R22(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π–π stacking interactions between the centroids of the benzene and furan rings of their 2,3-dihydro-1-benzofuran ring systems. Furthermore, there exists a C—H...π interaction that consolidates the crystal packing. A Hirshfeld surface analysis indicates that the most important contacts are H...H (40.7%), O...H/H...O (24.7%), C...H/H...C (16.1%) and C...C (8.8%).
ISSN:2056-9890

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