Synthesis of new Bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co(II), Ni(II) and Cu(II)

Synthesis of new Bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co(II), Ni(II) and Cu(II)

Abstract <br /> Bismuth metal react with dibenzothiazole disulfide (C7H4NS2)2 in refluxing toluene to give the compound Bi(S2C7H4N)3 through oxidative addition reaction, similary, a mixture of bismuth, (C7H4NS2)2 and iodine in 1:1:0.5 molar ratio in refluxing toluene lead to the formation of B...

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Main Authors: Nabeel. H. Buttrus, Z. U. Jassim
Format: Article
Language:Arabic
Published: College of Education for Pure Sciences 2009-06-01
Series:مجلة التربية والعلم
Online Access:https://edusj.mosuljournals.com/article_57684_30510327b5bc5bdea04a737b19fadf71.pdf
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spelling doaj-be77015cdb804eb38af28116a3c8dc5c2020-11-25T01:10:09ZaraCollege of Education for Pure Sciencesمجلة التربية والعلم1812-125X2664-25302009-06-012221810.33899/edusj.2009.5768457684Synthesis of new Bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co(II), Ni(II) and Cu(II)Nabeel. H. ButtrusZ. U. JassimAbstract <br /> Bismuth metal react with dibenzothiazole disulfide (C7H4NS2)2 in refluxing toluene to give the compound Bi(S2C7H4N)3 through oxidative addition reaction, similary, a mixture of bismuth, (C7H4NS2)2 and iodine in 1:1:0.5 molar ratio in refluxing toluene lead to the formation of Bi(S2C7H4N)2I. Adducts of new bismuth compounds with triphenyl-phosphine and 1,10-phenanthroline have been synthesized by direct reaction between the bismuth compounds and the neutral ligand. Trinuclear complexes of the general formula[Bi(S2C7H4N)3(MCl2)2] were prepared by a direct reaction of CoCl2.6H2O, NiCl2.6H2O or CuCl2.4H2O with bismuth compound. The bismuth compounds their adducts and the complexes have been characterized physico-chemically and spectro-scopically.https://edusj.mosuljournals.com/article_57684_30510327b5bc5bdea04a737b19fadf71.pdf
collection DOAJ
language Arabic
format Article
sources DOAJ
author Nabeel. H. Buttrus
Z. U. Jassim
spellingShingle Nabeel. H. Buttrus
Z. U. Jassim
Synthesis of new Bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co(II), Ni(II) and Cu(II)
مجلة التربية والعلم
author_facet Nabeel. H. Buttrus
Z. U. Jassim
author_sort Nabeel. H. Buttrus
title Synthesis of new Bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co(II), Ni(II) and Cu(II)
title_short Synthesis of new Bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co(II), Ni(II) and Cu(II)
title_full Synthesis of new Bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co(II), Ni(II) and Cu(II)
title_fullStr Synthesis of new Bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co(II), Ni(II) and Cu(II)
title_full_unstemmed Synthesis of new Bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co(II), Ni(II) and Cu(II)
title_sort synthesis of new bismuth (iii) compound and adducts of benzothiazol disulfide derivatives and their complexes with co(ii), ni(ii) and cu(ii)
publisher College of Education for Pure Sciences
series مجلة التربية والعلم
issn 1812-125X
2664-2530
publishDate 2009-06-01
description Abstract <br /> Bismuth metal react with dibenzothiazole disulfide (C7H4NS2)2 in refluxing toluene to give the compound Bi(S2C7H4N)3 through oxidative addition reaction, similary, a mixture of bismuth, (C7H4NS2)2 and iodine in 1:1:0.5 molar ratio in refluxing toluene lead to the formation of Bi(S2C7H4N)2I. Adducts of new bismuth compounds with triphenyl-phosphine and 1,10-phenanthroline have been synthesized by direct reaction between the bismuth compounds and the neutral ligand. Trinuclear complexes of the general formula[Bi(S2C7H4N)3(MCl2)2] were prepared by a direct reaction of CoCl2.6H2O, NiCl2.6H2O or CuCl2.4H2O with bismuth compound. The bismuth compounds their adducts and the complexes have been characterized physico-chemically and spectro-scopically.
url https://edusj.mosuljournals.com/article_57684_30510327b5bc5bdea04a737b19fadf71.pdf
work_keys_str_mv AT nabeelhbuttrus synthesisofnewbismuthiiicompoundandadductsofbenzothiazoldisulfidederivativesandtheircomplexeswithcoiiniiiandcuii
AT zujassim synthesisofnewbismuthiiicompoundandadductsofbenzothiazoldisulfidederivativesandtheircomplexeswithcoiiniiiandcuii
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