Bis(5-amino-2-chlorobenzoato-κO)triphenylantimony(V)
In the title compound, [Sb(C6H5)3(C7H5ClNO2)2], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxylate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intramolecular C—H...O interactions occur. The molecu...
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International Union of Crystallography
2009-11-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809043578 |
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doaj-be052494011b4bc5b94e86dc7786f9c32020-11-24T21:32:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1443m144310.1107/S1600536809043578Bis(5-amino-2-chlorobenzoato-κO)triphenylantimony(V)Liyuan WenHandong YinChuanhua WangIn the title compound, [Sb(C6H5)3(C7H5ClNO2)2], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxylate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intramolecular C—H...O interactions occur. The molecules are connected by intermolecular N—H...O, N—H...N and C—H...O hydrogen-bonding interactions and C—H...π stacking interactions, forming a three-dimensional supramolecular framework http://scripts.iucr.org/cgi-bin/paper?S1600536809043578 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Liyuan Wen Handong Yin Chuanhua Wang |
spellingShingle |
Liyuan Wen Handong Yin Chuanhua Wang Bis(5-amino-2-chlorobenzoato-κO)triphenylantimony(V) Acta Crystallographica Section E |
author_facet |
Liyuan Wen Handong Yin Chuanhua Wang |
author_sort |
Liyuan Wen |
title |
Bis(5-amino-2-chlorobenzoato-κO)triphenylantimony(V) |
title_short |
Bis(5-amino-2-chlorobenzoato-κO)triphenylantimony(V) |
title_full |
Bis(5-amino-2-chlorobenzoato-κO)triphenylantimony(V) |
title_fullStr |
Bis(5-amino-2-chlorobenzoato-κO)triphenylantimony(V) |
title_full_unstemmed |
Bis(5-amino-2-chlorobenzoato-κO)triphenylantimony(V) |
title_sort |
bis(5-amino-2-chlorobenzoato-κo)triphenylantimony(v) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2009-11-01 |
description |
In the title compound, [Sb(C6H5)3(C7H5ClNO2)2], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxylate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intramolecular C—H...O interactions occur. The molecules are connected by intermolecular N—H...O, N—H...N and C—H...O hydrogen-bonding interactions and C—H...π stacking interactions, forming a three-dimensional supramolecular framework |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809043578 |
work_keys_str_mv |
AT liyuanwen bis5amino2chlorobenzoatoamp954otriphenylantimonyv AT handongyin bis5amino2chlorobenzoatoamp954otriphenylantimonyv AT chuanhuawang bis5amino2chlorobenzoatoamp954otriphenylantimonyv |
_version_ |
1725958223715893248 |