Low Temperature Synthesis of Nest-Like Microsphere with Exposed (001) Facets and Its Enhanced Photocatalytic Performance by NaOH Alkalization

• Main Authors: Chentao Hou, Jiaming Zhu, Qiaoqiao Song
• Format: Article
• Language: English
• Published: MDPI AG 2018-02-01
• Series: Catalysts
• Subjects: F-TiO2; OH-TiO2; (001)TiO2; methylene blue; nest-like
• Online Access: http://www.mdpi.com/2073-4344/8/2/70

In this study, we completed a simple low-temperature synthesis of nest-like titanium oxide (TiO2) microspheres with exposed (001) facets. For the first time, the photocatalytic performance was enhanced by sodium hydroxide (NaOH) alkalization. The characterization of as-synthesized F-TiO2 and OH-TiO2 were analyzed by field emission scanning electron microscopy, high-resolution transmission electron microscopy, X-ray diffraction, fourier transform infrared spectroscopic analysis, ultraviolet-vis diffuse reflection spectra and Raman spectroscopy. The photocatalytic activity of the as-prepared catalyst was evaluated through the photocatalytic degradation of methylene blue (MB) and Rhodamine B (RhB) under simulated solar light. The results showed that modification using NaOH can lead to an increase in the percentage of (001) facets from 27.8% for F-TiO2 to 39.2% for OH-TiO2. OH-TiO2 showed superior catalytic photoactivity toward MB. The mechanism of NaOH on TiO2 is also discussed.