Di-μ-chlorido-bis[(2-amino-4-methylpyridine-κN)chloridomercury(II)]

Di-μ-chlorido-bis[(2-amino-4-methylpyridine-κN)chloridomercury(II)]

In the centrosymmetric dinuclear title compound, [Hg2Cl4(C6H8N2)2], the HgII ion is four-coordinated by one pyridine N atom from a 2-amino-4-methylpyridine ligand, one terminal Cl atom and two bridging Cl atoms. A distorted tetrahedral geometry is formed around each HgII ion. The crystal packing is...

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Main Authors: Azadeh Tadjarodi, Keyvan Bijanzad, Behrouz Notash
Format: Article
Language:English
Published: International Union of Crystallography 2012-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812039803
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spelling doaj-bddf935557f2498b8c3e6f69a51f18b52020-11-25T02:01:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1300m130110.1107/S1600536812039803Di-μ-chlorido-bis[(2-amino-4-methylpyridine-κN)chloridomercury(II)]Azadeh TadjarodiKeyvan BijanzadBehrouz NotashIn the centrosymmetric dinuclear title compound, [Hg2Cl4(C6H8N2)2], the HgII ion is four-coordinated by one pyridine N atom from a 2-amino-4-methylpyridine ligand, one terminal Cl atom and two bridging Cl atoms. A distorted tetrahedral geometry is formed around each HgII ion. The crystal packing is stabilized by intra- and intermolecular N—H...Cl hydrogen bonding. There are also π–π stacking interactions in the structure, with centroid-to-centroid distances of 3.594 (6) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536812039803
collection DOAJ
language English
format Article
sources DOAJ
author Azadeh Tadjarodi
Keyvan Bijanzad
Behrouz Notash
spellingShingle Azadeh Tadjarodi
Keyvan Bijanzad
Behrouz Notash
Di-μ-chlorido-bis[(2-amino-4-methylpyridine-κN)chloridomercury(II)]
Acta Crystallographica Section E
author_facet Azadeh Tadjarodi
Keyvan Bijanzad
Behrouz Notash
author_sort Azadeh Tadjarodi
title Di-μ-chlorido-bis[(2-amino-4-methylpyridine-κN)chloridomercury(II)]
title_short Di-μ-chlorido-bis[(2-amino-4-methylpyridine-κN)chloridomercury(II)]
title_full Di-μ-chlorido-bis[(2-amino-4-methylpyridine-κN)chloridomercury(II)]
title_fullStr Di-μ-chlorido-bis[(2-amino-4-methylpyridine-κN)chloridomercury(II)]
title_full_unstemmed Di-μ-chlorido-bis[(2-amino-4-methylpyridine-κN)chloridomercury(II)]
title_sort di-μ-chlorido-bis[(2-amino-4-methylpyridine-κn)chloridomercury(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-10-01
description In the centrosymmetric dinuclear title compound, [Hg2Cl4(C6H8N2)2], the HgII ion is four-coordinated by one pyridine N atom from a 2-amino-4-methylpyridine ligand, one terminal Cl atom and two bridging Cl atoms. A distorted tetrahedral geometry is formed around each HgII ion. The crystal packing is stabilized by intra- and intermolecular N—H...Cl hydrogen bonding. There are also π–π stacking interactions in the structure, with centroid-to-centroid distances of 3.594 (6) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812039803
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AT keyvanbijanzad diamp956chloridobis2amino4methylpyridineamp954nchloridomercuryii
AT behrouznotash diamp956chloridobis2amino4methylpyridineamp954nchloridomercuryii
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