5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate

5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate

In the title hydrated salt, C16H38N42+·2ClO4−·H2O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH3)2– groups. Within the cavity, there are two ammonium–amine N—H...N...

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Main Authors: Saroj K. S. Hazari, Tapashi G. Roy, Babul Chandra Nath, Prashun G. Roy, Seik Weng Ng, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812012135
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spelling doaj-bdd54d61950840848ea6db612c0895b42020-11-25T01:38:41ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684o1179o117910.1107/S16005368120121355,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrateSaroj K. S. HazariTapashi G. RoyBabul Chandra NathPrashun G. RoySeik Weng NgEdward R. T. TiekinkIn the title hydrated salt, C16H38N42+·2ClO4−·H2O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH3)2– groups. Within the cavity, there are two ammonium–amine N—H...N hydrogen bonds. Supramolecular layers are formed in the crystal packing whereby the water molecule links two perchlorate anions, and the resultant aggregates are connected to the dications via N—H...O hydrogen bonds. Layers, with an undulating topology, stack along the a axis being connected by C—H...O interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536812012135
collection DOAJ
language English
format Article
sources DOAJ
author Saroj K. S. Hazari
Tapashi G. Roy
Babul Chandra Nath
Prashun G. Roy
Seik Weng Ng
Edward R. T. Tiekink
spellingShingle Saroj K. S. Hazari
Tapashi G. Roy
Babul Chandra Nath
Prashun G. Roy
Seik Weng Ng
Edward R. T. Tiekink
5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate
Acta Crystallographica Section E
author_facet Saroj K. S. Hazari
Tapashi G. Roy
Babul Chandra Nath
Prashun G. Roy
Seik Weng Ng
Edward R. T. Tiekink
author_sort Saroj K. S. Hazari
title 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate
title_short 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate
title_full 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate
title_fullStr 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate
title_full_unstemmed 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate
title_sort 5,7,7,12,14,14-hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-04-01
description In the title hydrated salt, C16H38N42+·2ClO4−·H2O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH3)2– groups. Within the cavity, there are two ammonium–amine N—H...N hydrogen bonds. Supramolecular layers are formed in the crystal packing whereby the water molecule links two perchlorate anions, and the resultant aggregates are connected to the dications via N—H...O hydrogen bonds. Layers, with an undulating topology, stack along the a axis being connected by C—H...O interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812012135
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AT tapashigroy 577121414hexamethyl411diaza18diazoniacyclotetradecanebisperchloratemonohydrate
AT babulchandranath 577121414hexamethyl411diaza18diazoniacyclotetradecanebisperchloratemonohydrate
AT prashungroy 577121414hexamethyl411diaza18diazoniacyclotetradecanebisperchloratemonohydrate
AT seikwengng 577121414hexamethyl411diaza18diazoniacyclotetradecanebisperchloratemonohydrate
AT edwardrttiekink 577121414hexamethyl411diaza18diazoniacyclotetradecanebisperchloratemonohydrate
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