5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate

5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate

In the title hydrated salt, C16H38N42+·2ClO4−·H2O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH3)2– groups. Within the cavity, there are two ammonium–amine N—H...N...

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Bibliographic Details
Main Authors: Saroj K. S. Hazari, Tapashi G. Roy, Babul Chandra Nath, Prashun G. Roy, Seik Weng Ng, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812012135
Description
Summary:In the title hydrated salt, C16H38N42+·2ClO4−·H2O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH3)2– groups. Within the cavity, there are two ammonium–amine N—H...N hydrogen bonds. Supramolecular layers are formed in the crystal packing whereby the water molecule links two perchlorate anions, and the resultant aggregates are connected to the dications via N—H...O hydrogen bonds. Layers, with an undulating topology, stack along the a axis being connected by C—H...O interactions.
ISSN:1600-5368

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