Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate
The carbamate and hydrazone groups in the title compound, C18H18N4O6, are approximately orthogonal [dihedral angle = 83.3 (4)°], and the carbonyl groups are effectively anti [O=C...C=O torsion angle = −116.2 (7)°]. The conformation...
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International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810027273 |
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doaj-bdae7cb743ba47d7969d99e332414afd2020-11-25T02:30:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668o2023o202410.1107/S1600536810027273Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamateMarcus V. N. de SouzaAlessandra C. PinheiroEdward R. T. TiekinkSolange M. S. V. WardellJames L. WardellThe carbamate and hydrazone groups in the title compound, C18H18N4O6, are approximately orthogonal [dihedral angle = 83.3 (4)°], and the carbonyl groups are effectively anti [O=C...C=O torsion angle = −116.2 (7)°]. The conformation about the imine bond [1.295 (11) Å] is E. The crystal packing is dominated by O—H...O and N—H...O hydrogen bonding, which leads to two-dimensional arrays in the ab plane. http://scripts.iucr.org/cgi-bin/paper?S1600536810027273 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Marcus V. N. de Souza Alessandra C. Pinheiro Edward R. T. Tiekink Solange M. S. V. Wardell James L. Wardell |
| spellingShingle |
Marcus V. N. de Souza Alessandra C. Pinheiro Edward R. T. Tiekink Solange M. S. V. Wardell James L. Wardell Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate Acta Crystallographica Section E |
| author_facet |
Marcus V. N. de Souza Alessandra C. Pinheiro Edward R. T. Tiekink Solange M. S. V. Wardell James L. Wardell |
| author_sort |
Marcus V. N. de Souza |
| title |
Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title_short |
Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title_full |
Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title_fullStr |
Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title_full_unstemmed |
Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title_sort |
benzyl n-{(1s)-2-hydroxy-1-[n′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2010-08-01 |
| description |
The carbamate and hydrazone groups in the title compound, C18H18N4O6, are approximately orthogonal [dihedral angle = 83.3 (4)°], and the carbonyl groups are effectively anti [O=C...C=O torsion angle = −116.2 (7)°]. The conformation about the imine bond [1.295 (11) Å] is E. The crystal packing is dominated by O—H...O and N—H...O hydrogen bonding, which leads to two-dimensional arrays in the ab plane. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810027273 |
| work_keys_str_mv |
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