4-Cyclopropyl-1-(6′-deoxy-1′,2′-O-isopropylidene-α-d-glucofuranosyl)-1H-1,2,3-triazole
In the title compound, C14H21N3O5, the tetrahydrofuran ring adopts an envelope conformation with the C atom bearing the substituent as the flap. The pentafuranose ring adopts a twisted conformation about the C—C bond fusing the rings. The dihedral angle between these rings (all atoms), whi...
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| Language: | English |
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International Union of Crystallography
2013-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813021351 |
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doaj-bd9772eb5f294feeb209319f645cc94c2020-11-25T00:51:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-09-01699o1386o138610.1107/S16005368130213514-Cyclopropyl-1-(6′-deoxy-1′,2′-O-isopropylidene-α-d-glucofuranosyl)-1H-1,2,3-triazoleQiurong ZhangPeng HeGuangqiang ZhouKang YuHongmin LiuIn the title compound, C14H21N3O5, the tetrahydrofuran ring adopts an envelope conformation with the C atom bearing the substituent as the flap. The pentafuranose ring adopts a twisted conformation about the C—C bond fusing the rings. The dihedral angle between these rings (all atoms), which are cis fused, is 72.89 (14)°. The cyclopropane ring is disordered over two orientations in a 0.576 (5):0.424 (5) ratio; the dihedral angles subtended to the triazole ring are 53.3 (11) and 46.6 (9)°, respectively. In the crystal, the molecules are linked by O—H...N and O—H...O hydrogen bonds, generating (001) sheets. A weak C—H...O interaction also occurs.http://scripts.iucr.org/cgi-bin/paper?S1600536813021351 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Qiurong Zhang Peng He Guangqiang Zhou Kang Yu Hongmin Liu |
| spellingShingle |
Qiurong Zhang Peng He Guangqiang Zhou Kang Yu Hongmin Liu 4-Cyclopropyl-1-(6′-deoxy-1′,2′-O-isopropylidene-α-d-glucofuranosyl)-1H-1,2,3-triazole Acta Crystallographica Section E |
| author_facet |
Qiurong Zhang Peng He Guangqiang Zhou Kang Yu Hongmin Liu |
| author_sort |
Qiurong Zhang |
| title |
4-Cyclopropyl-1-(6′-deoxy-1′,2′-O-isopropylidene-α-d-glucofuranosyl)-1H-1,2,3-triazole |
| title_short |
4-Cyclopropyl-1-(6′-deoxy-1′,2′-O-isopropylidene-α-d-glucofuranosyl)-1H-1,2,3-triazole |
| title_full |
4-Cyclopropyl-1-(6′-deoxy-1′,2′-O-isopropylidene-α-d-glucofuranosyl)-1H-1,2,3-triazole |
| title_fullStr |
4-Cyclopropyl-1-(6′-deoxy-1′,2′-O-isopropylidene-α-d-glucofuranosyl)-1H-1,2,3-triazole |
| title_full_unstemmed |
4-Cyclopropyl-1-(6′-deoxy-1′,2′-O-isopropylidene-α-d-glucofuranosyl)-1H-1,2,3-triazole |
| title_sort |
4-cyclopropyl-1-(6′-deoxy-1′,2′-o-isopropylidene-α-d-glucofuranosyl)-1h-1,2,3-triazole |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2013-09-01 |
| description |
In the title compound, C14H21N3O5, the tetrahydrofuran ring adopts an envelope conformation with the C atom bearing the substituent as the flap. The pentafuranose ring adopts a twisted conformation about the C—C bond fusing the rings. The dihedral angle between these rings (all atoms), which are cis fused, is 72.89 (14)°. The cyclopropane ring is disordered over two orientations in a 0.576 (5):0.424 (5) ratio; the dihedral angles subtended to the triazole ring are 53.3 (11) and 46.6 (9)°, respectively. In the crystal, the molecules are linked by O—H...N and O—H...O hydrogen bonds, generating (001) sheets. A weak C—H...O interaction also occurs. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536813021351 |
| work_keys_str_mv |
AT qiurongzhang 4cyclopropyl168242deoxy1824228242oisopropylidene945dglucofuranosyl1h123triazole AT penghe 4cyclopropyl168242deoxy1824228242oisopropylidene945dglucofuranosyl1h123triazole AT guangqiangzhou 4cyclopropyl168242deoxy1824228242oisopropylidene945dglucofuranosyl1h123triazole AT kangyu 4cyclopropyl168242deoxy1824228242oisopropylidene945dglucofuranosyl1h123triazole AT hongminliu 4cyclopropyl168242deoxy1824228242oisopropylidene945dglucofuranosyl1h123triazole |
| _version_ |
1725245781439414272 |