| Summary: | Incident angle variation of light from the sun is a critical factor for the practical utilizations of solar energy devices. These devices typically receive the zenith of photon density under a solar elevation angle of 90°, and dramatic deletion of light density along with the decrease of solar elevation angle. Photonic crystals (PCs) with long range ordered arrays possess the controllable position of the photonic stop band (PSB) reliant on several factors, including incident angles, based on the Bragg–Snell law. The multiple scattering, refraction and inhibition of charge carrier recombination within the PSB suggests the potential capability for improving the efficiency of photoactive materials. In this work, we focus on the multiple scattering and refraction effects of PCs. A photoelectrode based on photonic crystal fluorine-doped tin oxide (PC FTO) film was fabricated, which allows the embedded photoactive materials (CdS nanoparticles) to benefit from the features of PCs under variable incidence, especially under lower incidence. The photoelectrode thus has enhanced overall photoelectrochemical (PEC) efficiency in different seasons, even if the increased surface area factor is deducted.
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