The Influence of HCl Concentration on the Rate of the Hydrolysis–Condensation Reaction of Phenyltrichlorosilane and the Yield of (Tetrahydroxy)(Tetraphenyl)Cyclotetrasiloxanes, Synthesis of All Its Geometrical Isomers and Thermal Self-Condensation of Them under “Pseudo”-Equilibrium Conditions

The Influence of HCl Concentration on the Rate of the Hydrolysis–Condensation Reaction of Phenyltrichlorosilane and the Yield of (Tetrahydroxy)(Tetraphenyl)Cyclotetrasiloxanes, Synthesis of All Its Geometrical Isomers and Thermal Self-Condensation of Them under “Pseudo”-Equilibrium Conditions

The rate of hydrolysis–condensation reaction of phenyltrichlorosilane in water-acetone solutions and the product yields were shown to significantly depend on the concentration of HCl (C<sub>HCl</sub>) in the solutions. The main product of the reaction was all-<i>cis-</i>(tetr...

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Bibliographic Details
Main Authors: Irina M. Petrova, Yury I. Lyakhovetsky, Nikolai S. Ikonnikov, Nataliya N. Makarova
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Molecules
Subjects:
hydrolysis-condensation
self-condensation
“pseudo”-equilibrium conditions
phenyltrichlorosilane
isomers of (tetrahydroxy)(tetraphenyl)tetrasiloxane
cage-like compounds
Online Access:https://www.mdpi.com/1420-3049/26/14/4383

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