An Excursion into the Intriguing World of Polymeric Tl(I) and Ag(I) Cyanoximates
The reaction of hot (~95 °C) aqueous solutions of Tl2CO3 with solid HL (HL = NC-C(=N-OH)-R is a cyanoxime, and R is an electron-withdrawing group; 37 ligands are known up-to-date) leads to crystalline yellow/orange TlL. Similarly, the reaction between AgNO3 and ML (M = K+, Na+; L = anion of the mono...
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| Format: | Article |
| Language: | English |
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MDPI AG
2011-09-01
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| Series: | Polymers |
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| Online Access: | http://www.mdpi.com/2073-4360/3/3/1475/ |