Synthesis of a high-grade lubricant from sunflower oil methyl esters
This paper presents the synthesis of saturated branched fatty acid methyl esters by codimerization of ethylene with conjugated linoleic methyl esters from sunflower oil. The catalytic system used is composed of iron, diimine and a reducing agent. This four-step synthesis will be discussed. After a l...
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| Format: | Article |
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EDP Sciences
2003-09-01
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| Series: | Oléagineux, Corps gras, Lipides |
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| Online Access: | http://dx.doi.org/10.1051/ocl.2003.0370 |
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doaj-bc988ffa64b142d3aeff7d94a23409ac2021-04-02T04:16:43ZengEDP SciencesOléagineux, Corps gras, Lipides1258-82101950-697X2003-09-01105-637037210.1051/ocl.2003.0370ocl2003105-6p370Synthesis of a high-grade lubricant from sunflower oil methyl estersHillion GérardProriol DavidThis paper presents the synthesis of saturated branched fatty acid methyl esters by codimerization of ethylene with conjugated linoleic methyl esters from sunflower oil. The catalytic system used is composed of iron, diimine and a reducing agent. This four-step synthesis will be discussed. After a last step of transesterification with TMP (trimethylolpropane) a lubricant with interesting characteristics (in particular a high thermal stability and a good cold behavior) is obtainedhttp://dx.doi.org/10.1051/ocl.2003.0370esters branchés saturéscodimérisationéthylèneTMPlubrifiant |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Hillion Gérard Proriol David |
| spellingShingle |
Hillion Gérard Proriol David Synthesis of a high-grade lubricant from sunflower oil methyl esters Oléagineux, Corps gras, Lipides esters branchés saturés codimérisation éthylène TMP lubrifiant |
| author_facet |
Hillion Gérard Proriol David |
| author_sort |
Hillion Gérard |
| title |
Synthesis of a high-grade lubricant from sunflower oil methyl esters |
| title_short |
Synthesis of a high-grade lubricant from sunflower oil methyl esters |
| title_full |
Synthesis of a high-grade lubricant from sunflower oil methyl esters |
| title_fullStr |
Synthesis of a high-grade lubricant from sunflower oil methyl esters |
| title_full_unstemmed |
Synthesis of a high-grade lubricant from sunflower oil methyl esters |
| title_sort |
synthesis of a high-grade lubricant from sunflower oil methyl esters |
| publisher |
EDP Sciences |
| series |
Oléagineux, Corps gras, Lipides |
| issn |
1258-8210 1950-697X |
| publishDate |
2003-09-01 |
| description |
This paper presents the synthesis of saturated branched fatty acid methyl esters by codimerization of ethylene with conjugated linoleic methyl esters from sunflower oil. The catalytic system used is composed of iron, diimine and a reducing agent. This four-step synthesis will be discussed. After a last step of transesterification with TMP (trimethylolpropane) a lubricant with interesting characteristics (in particular a high thermal stability and a good cold behavior) is obtained |
| topic |
esters branchés saturés codimérisation éthylène TMP lubrifiant |
| url |
http://dx.doi.org/10.1051/ocl.2003.0370 |
| work_keys_str_mv |
AT hilliongerard synthesisofahighgradelubricantfromsunfloweroilmethylesters AT prorioldavid synthesisofahighgradelubricantfromsunfloweroilmethylesters |
| _version_ |
1724173405410820096 |