{Bis[2-(3,5-dimethylpyrazol-1-yl-κN2)ethyl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate

{Bis[2-(3,5-dimethylpyrazol-1-yl-κN2)ethyl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate

The title compound, [PdCl(C14H23N5)]Cl·0.25H2O, is a pseudopolymorph of the previously reported compound [PdCl(C14H23N5)]Cl·2H2O [de Mendoza et al. (2006). Acta Cryst. E62, m2934–m2936]. The cationic complex and chloride anion are disordered over two positions...

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Main Authors: James Darkwa, Nangamso Miti, Lara C. Spencer, Ilia A. Guzei
Format: Article
Language:English
Published: International Union of Crystallography 2010-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810035427
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spelling doaj-bc92ce2e0375489ba0255c2b3a5bb73c2020-11-25T00:59:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1243m124310.1107/S1600536810035427{Bis[2-(3,5-dimethylpyrazol-1-yl-κN2)ethyl]amine-κN}chloridopalladium(II) chloride 0.25-hydrateJames DarkwaNangamso MitiLara C. SpencerIlia A. GuzeiThe title compound, [PdCl(C14H23N5)]Cl·0.25H2O, is a pseudopolymorph of the previously reported compound [PdCl(C14H23N5)]Cl·2H2O [de Mendoza et al. (2006). Acta Cryst. E62, m2934–m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups. http://scripts.iucr.org/cgi-bin/paper?S1600536810035427
collection DOAJ
language English
format Article
sources DOAJ
author James Darkwa
Nangamso Miti
Lara C. Spencer
Ilia A. Guzei
spellingShingle James Darkwa
Nangamso Miti
Lara C. Spencer
Ilia A. Guzei
{Bis[2-(3,5-dimethylpyrazol-1-yl-κN2)ethyl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
Acta Crystallographica Section E
author_facet James Darkwa
Nangamso Miti
Lara C. Spencer
Ilia A. Guzei
author_sort James Darkwa
title {Bis[2-(3,5-dimethylpyrazol-1-yl-κN2)ethyl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title_short {Bis[2-(3,5-dimethylpyrazol-1-yl-κN2)ethyl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title_full {Bis[2-(3,5-dimethylpyrazol-1-yl-κN2)ethyl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title_fullStr {Bis[2-(3,5-dimethylpyrazol-1-yl-κN2)ethyl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title_full_unstemmed {Bis[2-(3,5-dimethylpyrazol-1-yl-κN2)ethyl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title_sort {bis[2-(3,5-dimethylpyrazol-1-yl-κn2)ethyl]amine-κn}chloridopalladium(ii) chloride 0.25-hydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-10-01
description The title compound, [PdCl(C14H23N5)]Cl·0.25H2O, is a pseudopolymorph of the previously reported compound [PdCl(C14H23N5)]Cl·2H2O [de Mendoza et al. (2006). Acta Cryst. E62, m2934–m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810035427
work_keys_str_mv AT jamesdarkwa bis235dimethylpyrazol1ylamp954n2ethylamineamp954nchloridopalladiumiichloride025hydrate
AT nangamsomiti bis235dimethylpyrazol1ylamp954n2ethylamineamp954nchloridopalladiumiichloride025hydrate
AT laracspencer bis235dimethylpyrazol1ylamp954n2ethylamineamp954nchloridopalladiumiichloride025hydrate
AT iliaaguzei bis235dimethylpyrazol1ylamp954n2ethylamineamp954nchloridopalladiumiichloride025hydrate
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