Trichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(III) methanol hemisolvate

Trichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(III) methanol hemisolvate

The title compound, [FeCl3(C12H18N4)]·0.5CH3OH, contains an FeIII ion in a distorted octahedral coordination environment. The neutral N,N′,N′′-tridentate ligand adopts a fac coordination mode, and chloride ligands lie trans to each of the three...

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Main Authors: Anne Nielsen, Christine J. McKenzie, Andrew D. Bond
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680904375X
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spelling doaj-bc6d5468ab794f469adf926d9489907c2020-11-24T21:32:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1437m143710.1107/S160053680904375XTrichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(III) methanol hemisolvateAnne NielsenChristine J. McKenzieAndrew D. BondThe title compound, [FeCl3(C12H18N4)]·0.5CH3OH, contains an FeIII ion in a distorted octahedral coordination environment. The neutral N,N′,N′′-tridentate ligand adopts a fac coordination mode, and chloride ligands lie trans to each of the three coordinated N atoms. In the crystal, the complexes form columns extending parallel to the approximate local threefold axes of the FeN3Cl3 octahedra, and the columns are arranged so that the uncoordinated nitrile groups align in an antiparallel manner and the pyridyl rings form offset face-to-face arrangements [interplanar separations = 2.95 (1) and 3.11 (1) Å; centroid–centroid distances = 5.31 (1) and 4.92 (1) Å]. The methanol solvent molecule is disordered about a twofold rotation axis. http://scripts.iucr.org/cgi-bin/paper?S160053680904375X
collection DOAJ
language English
format Article
sources DOAJ
author Anne Nielsen
Christine J. McKenzie
Andrew D. Bond
spellingShingle Anne Nielsen
Christine J. McKenzie
Andrew D. Bond
Trichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(III) methanol hemisolvate
Acta Crystallographica Section E
author_facet Anne Nielsen
Christine J. McKenzie
Andrew D. Bond
author_sort Anne Nielsen
title Trichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(III) methanol hemisolvate
title_short Trichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(III) methanol hemisolvate
title_full Trichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(III) methanol hemisolvate
title_fullStr Trichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(III) methanol hemisolvate
title_full_unstemmed Trichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(III) methanol hemisolvate
title_sort trichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(iii) methanol hemisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description The title compound, [FeCl3(C12H18N4)]·0.5CH3OH, contains an FeIII ion in a distorted octahedral coordination environment. The neutral N,N′,N′′-tridentate ligand adopts a fac coordination mode, and chloride ligands lie trans to each of the three coordinated N atoms. In the crystal, the complexes form columns extending parallel to the approximate local threefold axes of the FeN3Cl3 octahedra, and the columns are arranged so that the uncoordinated nitrile groups align in an antiparallel manner and the pyridyl rings form offset face-to-face arrangements [interplanar separations = 2.95 (1) and 3.11 (1) Å; centroid–centroid distances = 5.31 (1) and 4.92 (1) Å]. The methanol solvent molecule is disordered about a twofold rotation axis.
url http://scripts.iucr.org/cgi-bin/paper?S160053680904375X
work_keys_str_mv AT annenielsen trichloridomethyl2methyl2pyridylmethylaminoethylaminoacetonitrileironiiimethanolhemisolvate
AT christinejmckenzie trichloridomethyl2methyl2pyridylmethylaminoethylaminoacetonitrileironiiimethanolhemisolvate
AT andrewdbond trichloridomethyl2methyl2pyridylmethylaminoethylaminoacetonitrileironiiimethanolhemisolvate
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