Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine

Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine

Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes were prepared by template reaction of 5-acetyl 2,4-dihydroxyacetophenone (H2-ADA) and ethylenediamine in the presence of metal ions. The complexes have been characterized on the basis of elemental analyses, conductivity, magnetic...

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Main Authors: Pulimamidi Saritha Reddy, P. V. Ananthalakshmi, V. Jayatyagaraju
Format: Article
Language:English
Published: Hindawi Limited 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/536269
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spelling doaj-bc284e01d2154e24af7a36fca93aea982020-11-24T20:48:56ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102011-01-018141542010.1155/2011/536269Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and EthylenediaminePulimamidi Saritha Reddy0P. V. Ananthalakshmi1V. Jayatyagaraju2Department of Chemistry, University College for Women, Osmania University, Hyderabad-500001, Andhra Pradesh, IndiaDepartment of Chemistry, University College for Women, Osmania University, Hyderabad-500001, Andhra Pradesh, IndiaDepartment of Chemistry, Addis Ababa University, P.O .Box 1176, Addis Ababa, EthiopiaCr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes were prepared by template reaction of 5-acetyl 2,4-dihydroxyacetophenone (H2-ADA) and ethylenediamine in the presence of metal ions. The complexes have been characterized on the basis of elemental analyses, conductivity, magnetic moments, infrared and electronic spectral data. The Schiff base binds to metal ions in bis-multidentate ONNO mode leading to two dimensional Schiff base polymers. All the complexes have been assigned octahedral stereochemistry.http://dx.doi.org/10.1155/2011/536269
collection DOAJ
language English
format Article
sources DOAJ
author Pulimamidi Saritha Reddy
P. V. Ananthalakshmi
V. Jayatyagaraju
spellingShingle Pulimamidi Saritha Reddy
P. V. Ananthalakshmi
V. Jayatyagaraju
Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine
E-Journal of Chemistry
author_facet Pulimamidi Saritha Reddy
P. V. Ananthalakshmi
V. Jayatyagaraju
author_sort Pulimamidi Saritha Reddy
title Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine
title_short Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine
title_full Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine
title_fullStr Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine
title_full_unstemmed Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine
title_sort synthesis and structural studies of first row transition metal complexes with tetradentate onno donor schiff base derived from 5-acetyl 2,4-dihydroxyacetophenone and ethylenediamine
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2011-01-01
description Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes were prepared by template reaction of 5-acetyl 2,4-dihydroxyacetophenone (H2-ADA) and ethylenediamine in the presence of metal ions. The complexes have been characterized on the basis of elemental analyses, conductivity, magnetic moments, infrared and electronic spectral data. The Schiff base binds to metal ions in bis-multidentate ONNO mode leading to two dimensional Schiff base polymers. All the complexes have been assigned octahedral stereochemistry.
url http://dx.doi.org/10.1155/2011/536269
work_keys_str_mv AT pulimamidisarithareddy synthesisandstructuralstudiesoffirstrowtransitionmetalcomplexeswithtetradentateonnodonorschiffbasederivedfrom5acetyl24dihydroxyacetophenoneandethylenediamine
AT pvananthalakshmi synthesisandstructuralstudiesoffirstrowtransitionmetalcomplexeswithtetradentateonnodonorschiffbasederivedfrom5acetyl24dihydroxyacetophenoneandethylenediamine
AT vjayatyagaraju synthesisandstructuralstudiesoffirstrowtransitionmetalcomplexeswithtetradentateonnodonorschiffbasederivedfrom5acetyl24dihydroxyacetophenoneandethylenediamine
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