The 1:1 charge-transfer complex dibenzotetrathiafulvalene–pyromellitic dianhydride (DBTTF–PMDA)

The 1:1 charge-transfer complex dibenzotetrathiafulvalene–pyromellitic dianhydride (DBTTF–PMDA)

The title charge-transfer (CT) complex, C10H2O6·C14H8S4, composed of donor dibenzotetrathiafulvalene (DBTTF) and acceptor pyromellitic dianhydride (PMDA), forms a mixed stacking pattern along the [-110] direction. The constituent molecules occupy crystallographic inversion centers. They are nearly p...

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Main Authors: Margaret E. Payne, Katelyn P. Goetz, Cynthia S. Day, Oana D. Jurchescu
Format: Article
Language:English
Published: International Union of Crystallography 2014-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814013324
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spelling doaj-bc1eeb4149864183aa97bceb20e1e8d52020-11-25T02:08:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-08-01708o844o84510.1107/S1600536814013324pk2526The 1:1 charge-transfer complex dibenzotetrathiafulvalene–pyromellitic dianhydride (DBTTF–PMDA)Margaret E. Payne0Katelyn P. Goetz1Cynthia S. Day2Oana D. Jurchescu3Department of Physics, Wake Forest University, Winston-Salem, NC 27109, USADepartment of Physics, Wake Forest University, Winston-Salem, NC 27109, USADepartment of Chemistry, Wake Forest University, Winston-Salem, NC 27109, USADepartment of Physics, Wake Forest University, Winston-Salem, NC 27109, USAThe title charge-transfer (CT) complex, C10H2O6·C14H8S4, composed of donor dibenzotetrathiafulvalene (DBTTF) and acceptor pyromellitic dianhydride (PMDA), forms a mixed stacking pattern along the [-110] direction. The constituent molecules occupy crystallographic inversion centers. They are nearly parallel and lie ca.3.41 Å from each other. The crystals exhibit a high degree of donor/acceptor overlap [88.20 (4)%] in the long direction of the DBTTF and PMDA molecules as compared with 51.27 (5)% in the shortest direction of the molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536814013324
collection DOAJ
language English
format Article
sources DOAJ
author Margaret E. Payne
Katelyn P. Goetz
Cynthia S. Day
Oana D. Jurchescu
spellingShingle Margaret E. Payne
Katelyn P. Goetz
Cynthia S. Day
Oana D. Jurchescu
The 1:1 charge-transfer complex dibenzotetrathiafulvalene–pyromellitic dianhydride (DBTTF–PMDA)
Acta Crystallographica Section E
author_facet Margaret E. Payne
Katelyn P. Goetz
Cynthia S. Day
Oana D. Jurchescu
author_sort Margaret E. Payne
title The 1:1 charge-transfer complex dibenzotetrathiafulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title_short The 1:1 charge-transfer complex dibenzotetrathiafulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title_full The 1:1 charge-transfer complex dibenzotetrathiafulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title_fullStr The 1:1 charge-transfer complex dibenzotetrathiafulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title_full_unstemmed The 1:1 charge-transfer complex dibenzotetrathiafulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title_sort 1:1 charge-transfer complex dibenzotetrathiafulvalene–pyromellitic dianhydride (dbttf–pmda)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-08-01
description The title charge-transfer (CT) complex, C10H2O6·C14H8S4, composed of donor dibenzotetrathiafulvalene (DBTTF) and acceptor pyromellitic dianhydride (PMDA), forms a mixed stacking pattern along the [-110] direction. The constituent molecules occupy crystallographic inversion centers. They are nearly parallel and lie ca.3.41 Å from each other. The crystals exhibit a high degree of donor/acceptor overlap [88.20 (4)%] in the long direction of the DBTTF and PMDA molecules as compared with 51.27 (5)% in the shortest direction of the molecules.
url http://scripts.iucr.org/cgi-bin/paper?S1600536814013324
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