Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvate

Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvate

In the title compound, [Pd(C17H14N3S2)2]·2C3H7NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The PdII ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-plana...

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Main Authors: Hapipah Mohd Ali, Hamid Khaledi
Format: Article
Language:English
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810051780
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spelling doaj-bbea1f5724314d57b6255e25b238e23a2020-11-25T00:51:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m84m8410.1107/S1600536810051780Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvateHapipah Mohd AliHamid KhalediIn the title compound, [Pd(C17H14N3S2)2]·2C3H7NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The PdII ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethylformamide (DMF) solvent molecules via an N—H...O interaction. In addition, C—H...S interactions are observed. http://scripts.iucr.org/cgi-bin/paper?S1600536810051780
collection DOAJ
language English
format Article
sources DOAJ
author Hapipah Mohd Ali
Hamid Khaledi
spellingShingle Hapipah Mohd Ali
Hamid Khaledi
Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvate
Acta Crystallographica Section E
author_facet Hapipah Mohd Ali
Hamid Khaledi
author_sort Hapipah Mohd Ali
title Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvate
title_short Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvate
title_full Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvate
title_fullStr Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvate
title_full_unstemmed Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvate
title_sort bis{benzyl 3-[(1h-indol-3-yl)methylidene]dithiocarbazato-κ2n3,s}palladium(ii) n,n-dimethylformamide disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-01-01
description In the title compound, [Pd(C17H14N3S2)2]·2C3H7NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The PdII ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethylformamide (DMF) solvent molecules via an N—H...O interaction. In addition, C—H...S interactions are observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810051780
work_keys_str_mv AT hapipahmohdali bisbenzyl31hindol3ylmethylidenedithiocarbazatoamp9542n3spalladiumiinndimethylformamidedisolvate
AT hamidkhaledi bisbenzyl31hindol3ylmethylidenedithiocarbazatoamp9542n3spalladiumiinndimethylformamidedisolvate
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